Study on Mesoporous PW/SBA-15 for Isomerization of α-Pinene

Article Preview

Abstract:

SBA-15 supported phosphotungstic acid has been synthesized under hydrothermal conditions via pH adjustment and characterized with various analytical and spectroscopic techniques including X-ray diffraction (XRD), N2 adsorption, transmission electron micrographs (TEM). XRD results indicate that the substitution of tungsten occurs in the silicate framework structure of SBA-15. Study on the catalytic activity of mesoporous PW/SBA-15 catalyst through the isomerization of the a-pinene was investigated. The best reactive conditions of a-pinene isomerization were follows: reaction temperature 130°C, dosage of PW/SBA-15 catalyst 2 %, reactive time 2 h. Then the rate of a-pinene conversion could achieve 94.56 %, the selectivity of camphene could achieve 48.5%.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

134-137

Citation:

Online since:

December 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] F. Özkan, G. Günduü, O. Akpolat, N. Besün, D. Murzin. Chem. Eng. J., Vol. 91, (2003), p.257.

Google Scholar

[2] M. Yadav, Ch. Chudasama, R. Jasra. J. Mol. Catal. A: Chem., Vol. 216, (2004), p.51.

Google Scholar

[3] G. Gündüz, R. Dimitrova, S. Yilmaz, L. Dimitrov, M. Spassova. J. Mol. Catal. A: Chem., Vol. 225, (2005), p.253.

Google Scholar

[4] M. Encormirr, K. Wilson, A. Lee. J. Catal., Vol. 215, (2003), p.57.

Google Scholar

[5] A. Allahverdiev, G. Gündüz, D. Murzin. Ind. Eng. Chem. Res., Vol. 37, (1998), 2373 A.

Google Scholar

[6] Severino, J. Esculsas, J. Rocha, et al. Appl. Catal. A: Gen., Vol. 142, (1996), p.255.

Google Scholar

[7] C.T. Kresge, M.E. Leonowicz W.J. Roth, J.C. Vartli, J.S. Beck, Nature. 359 (1992), p.710.

Google Scholar

[8] X. Yuan, J. Shen, G. Li, Chin. J. Catal. 23 (2002), p.9.

Google Scholar

[9] W. Liu, S.Y. Lai, H.X. Dai, S.J. Wang, H.Z. Sun, Catal. Today 131 (2008), p.450.

Google Scholar

[10] H.Y. Huang, C.L. Yang, H.X. Zhang, M.C. Liu, Micropor. Mesopor. Mater. 111(2008), p.254.

Google Scholar

[11] N. Petkov, N. Stock, T. Bein, J. Phys. Chem. B 109 (2005), p.10737.

Google Scholar

[12] S.S. Wu, J. Wang, W.H. Zhang, X.Q. Ren, Catal. Lett. 125 (2008), p.308.

Google Scholar

[13] R. van Grieken, J.A. Melero, G. Morales, Appl. Catal. A: Gen. 289 (2005), p.143.

Google Scholar

[14] M. Li, P.J. Pham, C.U. Pittman Jr, T.Y. Li, Anal. Sci. 24 (2008) , p.1245.

Google Scholar

[15] A. Lapkin, B. Bozkaya, T. Mays, L. Borello, Catal. Today 81 (2003) , p.616–618.

Google Scholar

[16] A. Corma, M. Iglesias, C. Del Pino, F. Sanchez, J. Chem. Soc., Chem. Commun. (1991), p.1253.

Google Scholar

[17] C.H. Wu, Y.J. Qin X.Y. Dai G.B. Du. Adv. Mater. Res. (2013), p.2475.

Google Scholar