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Study on Mesoporous PW/SBA-15 for Isomerization of α-Pinene
Abstract:
SBA-15 supported phosphotungstic acid has been synthesized under hydrothermal conditions via pH adjustment and characterized with various analytical and spectroscopic techniques including X-ray diffraction (XRD), N2 adsorption, transmission electron micrographs (TEM). XRD results indicate that the substitution of tungsten occurs in the silicate framework structure of SBA-15. Study on the catalytic activity of mesoporous PW/SBA-15 catalyst through the isomerization of the a-pinene was investigated. The best reactive conditions of a-pinene isomerization were follows: reaction temperature 130°C, dosage of PW/SBA-15 catalyst 2 %, reactive time 2 h. Then the rate of a-pinene conversion could achieve 94.56 %, the selectivity of camphene could achieve 48.5%.
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134-137
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December 2013
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© 2014 Trans Tech Publications Ltd. All Rights Reserved
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