The Synthesis and Optical Properties of Two BOPIMs Containing N,N-Dimethylaminophenyl Groups

Ming Xun Yan; Ping Shen; Wei Zhang; Jin Dong Gong; Chang Ying Yang

doi:10.4028/www.scientific.net/AMM.488-489.265

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 488-489The Synthesis and Optical Properties of Two BOPIMs...

The Synthesis and Optical Properties of Two BOPIMs Containing N,N-Dimethylaminophenyl Groups

Abstract:

The synthesis and nonlinear optical properties of two N, N-dimethylaminophenyl substituted BOPIMs, BOPIM-ma and BOPIM-dma, were investigated. A more significant solvatochromic shift is achieved in BOPIM-ma, which is more sensitive to solven. It is distinct that the energy gap between the HOMO and LUMO for BOPIM-ma, 2.503 ev, is larger than that of BOIM-dma, 2.449 ev, an indication of the functionalization of N,N-dimethylaminophenyl group.

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Periodical:

Applied Mechanics and Materials (Volumes 488-489)

Pages:

265-268

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.488-489.265

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Online since:

January 2014

Authors:

Ming Xun Yan, Ping Shen, Wei Zhang, Jin Dong Gong, Chang Ying Yang*

Keywords:

Band Gap, BOPIM-DMA, BOPIM-ma, Fluorescence, Twisted Intramolecular Charge Transfer (TICT)

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