Trans-Esterification of Triglycerides with Methanol on Sulfated Zirconia Prepared with Different Concentration of Sulfuric Acid

Abstract:

• Periodical: Applied Mechanics and Materials (Volume 493)
• Pages: 15-20
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.493.15
• Online since: January 2014
• Authors: Ramli Mat, Rubyatul Adawiyah Samsudin, Mahadhir Mohamed, Anwar Johari, Mohd Johari Kamaruddin, Asmadi Ali
• Keywords: Acidity, Bio-Diesel, Sulfated Zirconia, Trans-Esterification, Triacetin

References

[1] M.E. Borges, L. Daaz, Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review, Renewable and Sustainable Energy Reviews. 16 (2012) 2839-2849.

DOI: 10.1016/j.rser.2012.01.071

[2] R. Mat, R.A. Samsudin, M. Mohamed, A. Johari, Solid catalysts and their application in biodiesel production, Bulletin of Chemical Reaction Engineering and Catalysis. 7 (2012) 142-149.

DOI: 10.9767/bcrec.7.2.3047.142-149

[3] Z. Helwani, M.R. Othman, N. Aziz, J. Kim, W.J.N. Fernando, Solid heterogeneous catalysts for transesterification of triglycerides with methanol: A review, Applied Catalysis A: General. 363 (2009) 1-10.

DOI: 10.1016/j.apcata.2009.05.021

[4] Z. Wen, X. Yu, S. Tu, J. Yan, E. Dahlquist, Biodiesel production from waste cooking oil catalyzed by TiO2-MgO mixed oxides, Bioresource Technology. 101 (2010) 9570-9576.

DOI: 10.1016/j.biortech.2010.07.066

[5] G.J. Suppes, M.A. Dasari, E.J. Doskocil, P.J. Mankidy, and M.J. Goff, Transesterification of soybean oil with zeolite and metal catalysts. Applied Catalysis A: General. 257 (2004) 213-223.

DOI: 10.1016/j.apcata.2003.07.010

[6] S. Furuta, H. Matsuhashi, K. Arata, Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure. Catalysis Communications. 5 (2004) 721-723.

DOI: 10.1016/j.catcom.2004.09.001

[7] S. Triwahyono, Z. Abdullah, and A.A. Jalil, The Effect of Sulfate Ion on the Isomerization of n-Butane to iso-Butane. Journal of Natural Gas Chemistry. 15 (2006) 247-252.

DOI: 10.1016/s1003-9953(07)60001-2

[8] D. Rattanaphra, A.P. Harvey, A. Thanapimmetha, and P. Srinophakun, Simultaneous transesterification and esterification for biodiesel production with and without a sulphated zirconia catalyst, Fuel. 97 (2012) 467-475.

DOI: 10.1016/j.fuel.2012.01.031

[9] A. Patel, V. Brahmkhatri, and N. Singh, Biodiesel production by esterification of free fatty acid over sulfated zirconia. Renewable Energy, 51 (2013) 227-233.

DOI: 10.1016/j.renene.2012.09.040

[10] J. Kansedo, and K.T. Lee, Process optimization and kinetic study for biodiesel production from non-edible sea mango (Cerbera odollam) oil using response surface methodology. Chemical Engineering Journal. 214 (2013) 157-164.

DOI: 10.1016/j.cej.2012.10.048

[11] D. Farcasiu, J.Q. Li, and A. Kogelbauer, The mechanism of conversion of hydrocarbons on sulfated metal oxides. Part IV. Kinetics of the reaction of methylcyclopentane on sulfated zirconia. Journal of Molecular Catalysis A: Chemical. 124 (1997).

DOI: 10.1016/s1381-1169(97)00067-8

[12] P. Tynjala T.T. Pakkanen, Acidic properties of ZSM-5 zeolite modified with Ba2+, Al3+ and La3+ ion-exchange. Journal of Molecular Catalysis A: Chemical. 110 (1996) 153-161.

DOI: 10.1016/1381-1169(96)00159-8

[13] K.H. Chung, and B.G. Park, Esterification of oleic acid in soybean oil on zeolite catalysts with different acidity. Journal of Industrial and Engineering Chemistry 15 (2009) 388-392.

DOI: 10.1016/j.jiec.2008.11.012

[14] J.C. Yori, and J.M. Parera, n-Butane isomerization on metal-promoted sulfated zirconia. Applied Catalysis A: General. 147 (1996) 145-157.

DOI: 10.1016/s0926-860x(96)00214-1