Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen

Xido Dong Li; Xiao Feng Wang; Yuan Cheng Zhu; Mei Mei An

doi:10.4028/www.scientific.net/AMM.496-500.88

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 496-500Sheet Polymeric Iron (III) Porphyrin Complexes...

Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen

Abstract:

The sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.

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Periodical:

Applied Mechanics and Materials (Volumes 496-500)

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88-91

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.496-500.88

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Online since:

January 2014

Authors:

Xido Dong Li*, Xiao Feng Wang, Yuan Cheng Zhu, Mei Mei An

Keywords:

Catalytic Oxidation, Molecular Oxygen, PFe(III) TPP Complex, Styrene

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