Recycling and Synthesis of Li(Ni1/3Co1/3Mn1/3)O2 from Used Power Battery by Electrolytic Method

Ying Hao Xie; Hai Jun Yu; Yan Nan Ou; Chang Dong Li

doi:10.4028/www.scientific.net/AMM.528.87

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 528Recycling and Synthesis of Li(Ni1/3Co1/3Mn1/3)O2...

Recycling and Synthesis of Li(Ni_1/3Co_1/3Mn_1/3)O₂ from Used Power Battery by Electrolytic Method

Abstract:

The Li(Ni_1/3Co_1/3Mn_1/3)O₂ cathode materials recover from used power battery synthesized using the electrolytic method to investigate its microstructure and electrochemical properties. The X-ray diffract ion (XRD) patterns of the prepared powders showed a hexagonal α–NaFeO₂ structure (space group: R-3m, 166) and the existence of Li₂MnO₃ phase in the composite structure. The morphology of the prepared powders consisted of spherical agglomerates with particle size varying from 5 to 18μm. The size increased with increasing the spacing of titanium plate electrodes. The observed discharge capacity for the Li(Ni_1/3Co_1/3Mn_1/3)O₂ electrode (the spacing of titanium plate electrodes is 5, 7.5, 10 mm) for the first cycle was 167, 150, and 121 mAhg^-1, respectively.

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Periodical:

Applied Mechanics and Materials (Volume 528)

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87-93

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https://doi.org/10.4028/www.scientific.net/AMM.528.87

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Online since:

February 2014

Authors:

Ying Hao Xie, Hai Jun Yu*, Yan Nan Ou, Chang Dong Li

Keywords:

Cathode Material, Li(Ni_1/3Co_1/3Mn_1/3)O₂, Lithium-Ion Battery, Recycling

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References

[1] H.J. Yu, T.Z. Zhang, J. Yuan, Trial study on EV battery recycling standardization development, Adv. Mater. Res. 610-613(2013) 2170-2173.

DOI: 10.4028/www.scientific.net/amr.610-613.2170

Google Scholar

[2] G. Granata, E. Moscardini, F. Pagnanelli, Product recovery from Li-ion battery wastes coming from an industrial pre-treatment plant: Lab scale tests and process simulations, J. Power Sources. 206 (2012) 393-401.

DOI: 10.1016/j.jpowsour.2012.01.115

Google Scholar

[3] H.J. Jeon, C.S. Kang, G.W. Yoo, The influence of lithium content in xLi[Li1/3Mn2/3]O2•(1-x)Li[NiaCobMn(1-a+b)]O2 cathode materials prepared by co-precipitation method. J. Electroceram. 30(2013) 1-7.

DOI: 10.1007/s10832-013-9780-5

Google Scholar

[4] G.C. Chen, X.C. Tang, Z.M. Wang, Recovery of Ni, Co and Mn from spent lithium ion batteries and preparation of LiCo1/3Ni1/3Mn1/3O2 cathode material. Chinese J. Inorg. Chem. 27 (2011) 1987-(1992).

Google Scholar

[5] L. Zhang, X. Wang, T. Muta, The effects of extra Li content, synthesis method, sintering temperature on synthesis and electrochemistry of layered LiNi1/3Mn1/3Co1/O2. J. Power Sources 162 (2006) 629-635.

DOI: 10.1016/j.jpowsour.2006.06.089

Google Scholar

[6] P.S. Whitfield, I.J. Davidson, L.M.D. Cranswick, Investigation of possible superstructure and cation disorder in the lithium battery cathode material LiMn1/3Ni1/3Co1/3O2 using neutron and anomalous dispersion powder diffraction, Solid State Ionics 176 (2005).

DOI: 10.1016/j.ssi.2004.07.066

Google Scholar

[7] J.R. Ying, J. Gao, C.Y. Jiang, Research and development of preparing spherical cathode materials for lithium ion batteries by controlled crystallization method. J. Inorg. Mater. 2 (2006) 291-297.

Google Scholar

[8] S. -H. Park, S. -T. Myung, C.S. Yoon, Synthesis of nanostructured Li[Ni1/3Co1/3Mn1/3]O2 via a modified carbonate process, Chem. Mater. 17 (2005) 6-8.

Google Scholar