Polymerization and Characterization of N-[o-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl] Methacrylamide

Zheng Fu; Long Hua Chen; Sheng Jun Li; Chao Yuan

doi:10.4028/www.scientific.net/AMM.536-537.1443

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 536-537Polymerization and Characterization of...

Polymerization and Characterization of N-[o-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl] Methacrylamide

Abstract:

A novel type of chiral methacrylamide derivative, N-[o-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl) phenyl]methacrylamide ((R)-PhOPMAM), was synthesized and radically polymerized to the corresponding polymers in moderate yields. The polymerization characteristics and the chiroptical behavior of the resultant polymers have been examined in detail by using IR and ¹H NMR spectroscopies in comparison with our previous observation. The polymers showed relatively high molecular weights(Mn=5000-10000) and large specific rotations([α]₂₅^D = -326.0°～-357.4°).

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Periodical:

Applied Mechanics and Materials (Volumes 536-537)

Pages:

1443-1446

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.536-537.1443

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Online since:

April 2014

Authors:

Zheng Fu, Long Hua Chen, Sheng Jun Li, Chao Yuan*

Keywords:

Methacrylamide, Optical Activity, Radical Polymerization, Specific Rotation

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