Mechanical Properties of Vinyl Ester Resin/Epoxidized Plam Oil/Nanoclay Composite

Article Preview

Abstract:

The aim of this study is to develop vinyl ester resin (VE) with enhanced mechanical and thermal properties. Nanocomposites vinyl ester resin (VE)/ epoxidized palm oil (EPO)/ clay were prepared at different amount of epoxidized palm oil (EPO) (5, 7.5 and 10 wt%) in presence of various ratio of clay (1,2 and 3 phr) by free radical polymerization. The curing agent for polymerizing nanocomposites was methyl ethyl ketone peroxide (MEKP). Studies on their mechanical and physical properties were carried out by tensile and flexural tests. The results obtained revealed interactions between the vinyl ester resin (VE) and epoxidized palm oil (EPO). Based on the results of tensile strength, the optimum loading content for EPO and clay was 5wt% and 1 phr, respectively. When the concentration of EPO increased, the ductility was improved, indicated higher toughness.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

165-169

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Silverajah, V., Ibrahim, N. A., Yunus, W. M. Z. W., Hassan, H. A. and Woei, C. B. (2012).

Google Scholar

[2] Fenollar, O., García, D., Sánchez, L., López, J. and Balart, R. (2009). Optimization Of The Curing Conditions of PVC Plastisols Based on the Use of an Epoxidized Fatty Acid Ester Plasticizer. European Polymer Journal. 45(9), pp.2674-2684.

DOI: 10.1016/j.eurpolymj.2009.05.029

Google Scholar

[3] La Scala, J. and Wool, R. P. (2005). Property Analysis of Triglyceride-Based Thermosets. Polymer. 46(1), pp.61-69.

DOI: 10.1016/j.polymer.2004.11.002

Google Scholar

[4] Fu, L., Yang, L., Dai, C., Zhao, C. and Ma, L. (2010). Thermal and Mechanical Properties of Acrylated Expoxidized Soybean Oil Based Thermosets. Journal of applied polymer science. 117(4), pp.2220-2225.

DOI: 10.1002/app.32126

Google Scholar

[5] Drozdov, A. D., Christiansen, J. d., Gupta, R. and Shah, A. (2003). Model for Anomalous Moisture Diffusion Through a Polymer–Clay Nanocomposite. Journal of Polymer Science Part B: Polymer Physics. 41(5), pp.476-492.

DOI: 10.1002/polb.10393

Google Scholar

[6] Shah, A. P., Gupta, R. K., Gangarao, H. V. and Powell, C. E. (2002). Moisture Diffusion Through Vinyl Ester Nanocomposites made with Montmorillonite Clay. Polymer Engineering & Science. 42(9), pp.1852-1863.

DOI: 10.1002/pen.11078

Google Scholar

[7] Ratna, D., Khan, S., Barman, S. and Chakraborty, B. (2012). Synthesis of Vinylester-Clay Nanocomposites: Influence of the Nature of Clay on Mechanical, Thermal and Barrier Properties. The Open Macromolecules Journal. 6, pp.59-67.

Google Scholar

[8] Zhao, X., Zhang, Q., Chen, D. and Lu, P. (2010). Enhanced Mechanical Properties of Graphene-Based Poly (Vinyl Alcohol) Composites. Macromolecules. 43(5), pp.2357-2363.

DOI: 10.1021/ma902862u

Google Scholar

[9] Chieng, B. W., Ibrahim, N. A., Wan Yunus, W. M. Z., Hussein, M. Z. and Silverajah, V. (2012).

Google Scholar

[10] Kim, I. -H., Lee, S. C. and Jeong, Y. G. (2009). Tensile Behavior and Structural Evolution of Poly (Lactic Acid) Monofilaments in Glass Transition Region. Fibers and Polymers. 10(5), pp.687-693.

DOI: 10.1007/s12221-010-0687-6

Google Scholar

[11] Ibrahim, N., Chieng, B. and Yunus, W. W. (2010).

Google Scholar

[12] Martin, O. and Averous, L. (2001). Poly (Lactic Acid): Plasticization and Properties of Biodegradable Multiphase Systems. Polymer. 42(14), pp.6209-6219.

DOI: 10.1016/s0032-3861(01)00086-6

Google Scholar