Effect of NaOH Concentration on the Strength of Non Sodium Silicate Fly Ash Geopolymer

Article Preview

Abstract:

The current work presents the effect of alkali concentration on fly ash based geopolymer material. In this work geopolymer material was prepared with a fixed Si/Al ratio (1.85: 1) and varied solid to water ratio and NaOH concentration. All samples were tested to establish the role of alkali on the strength. Samples prepared with 8M of NaOH showed the highest compressive strength. In this regards, Fourier transform infrared spectroscopy (FTIR) results support this observation where broad band becomes sharper and shifts towards lower wavenumbers. In XRD the broad hump slightly shifted towards higher values which indicate the formation of new product. These findings show that to obtain required processing time at desired mechanical strength for a specific application of geopolymer, the suitable concentration of alkali must be established.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

102-105

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Davidovits and D. Comrie, Long term durability of hazardous toxic and nuclear waste disposals, in 1st European Conference on Soft Mineralurgy, Compiegne, France, 1988, p.125–134.

Google Scholar

[2] D. Khale and R. Chaudhary, Mechanism of geopolymerization and factors influencing its development: a review, Journal of Materials Science, vol. 42, no. 3, p.729–746, Jan. (2007).

DOI: 10.1007/s10853-006-0401-4

Google Scholar

[3] Van Jaarsveld, J. G. S., J. S. J. Van Deventer, and LlLorenzen. Factors affecting the immobilization of metals in geopolymerizedflyash., Metallurgical and materials transactions B 29. 1 (1998): 283-291.

DOI: 10.1007/s11663-998-0032-z

Google Scholar

[4] Perera, D. S., Uchida, O., Vance, E. R., & Finnie, K. S. Influence of curing schedule on the integrity of geopolymers., Journal of materials science 42. 9 (2007): 3099-3106.

DOI: 10.1007/s10853-006-0533-6

Google Scholar

[5] Alonso, S., and A. Palomo. Alkaline activation of metakaolin and calcium hydroxide mixtures: influence of temperature, activator concentration and solids ratio., Materials Letters 47. 1 (2001): 55-62.

DOI: 10.1016/s0167-577x(00)00212-3

Google Scholar

[6] Oh, J. E., Monteiro, P. J., Jun, S. S., Choi, S., & Clark, S. M. The evolution of strength and crystalline phases for alkali-activated ground blast furnace slag and fly ash-based geopolymers., Cement and Concrete Research 40. 2 (2010): 189-196.

DOI: 10.1016/j.cemconres.2009.10.010

Google Scholar

[7] Kovalchuk, G., Ana Fernández-Jiménez, and A. Palomo. Alkali-activated fly ash: Effect of thermal curing conditions on mechanical and microstructural development–Part II., Fuel 86. 3 (2007): 315-322.

DOI: 10.1016/j.fuel.2006.07.010

Google Scholar

[8] Swanepoel, J. C., and C. A. Strydom. Utilisation of fly ash in a geopolymeric material., Applied Geochemistry 17. 8 (2002): 1143-1148.

DOI: 10.1016/s0883-2927(02)00005-7

Google Scholar

[9] Bakharev, T. Geopolymeric materials prepared using Class F fly ash and elevated temperature curing., Cement and Concrete Research 35. 6 (2005): 1224-1232.

DOI: 10.1016/j.cemconres.2004.06.031

Google Scholar

[10] He, Jian, et al. The strength and microstructure of two geopolymers derived from metakaolin and red mud-fly ash admixture: A comparative study., Construction and Building Materials 30 (2012): 80-91.

DOI: 10.1016/j.conbuildmat.2011.12.011

Google Scholar

[11] Zhang, Guoping, Jian He, and Robert P. Gambrell. Synthesis, characterization, and mechanical properties of red mud-based geopolymers., Transportation Research Record: Journal of the Transportation Research Board 2167. 1 (2010): 1-9.

DOI: 10.3141/2167-01

Google Scholar

[12] Zhang, Shuzheng, Kecheng Gong, and Jianwen Lu. Novel modification method for inorganic geopolymer by using water soluble organic polymers., Materials Letters 58. 7 (2004): 1292-1296.

DOI: 10.1016/j.matlet.2003.07.051

Google Scholar

[13] Fernández-Jiménez, Ana, and A. Palomo. Composition and microstructure of alkali activated fly ash binder: effect of the activator., Cement and Concrete Research 35. 10 (2005): 1984-(1992).

DOI: 10.1016/j.cemconres.2005.03.003

Google Scholar

[14] Bakharev, T. Geopolymeric materials prepared using Class F fly ash and elevated temperature curing., Cement and Concrete Research 35. 6 (2005): 1224-1232.

DOI: 10.1016/j.cemconres.2004.06.031

Google Scholar