Polyethersulfone (PES) Membranes for CO2/CH4 Separation: Effect of Polymer Blending

Article Preview

Abstract:

Effect of polymer blending on physico-chemical and gas permeation properties of polyethersulfone (PES) membrane was studied. PES was chosen as base polymer and polysulfone (PSF) and polyvinyl acetate (PVAc) were added as glassy and rubbery polymer additives respectively. The morphology, thermal stability and miscibility of PES membranes were characterized by FESEM, TGA and DSC respectively to observe the effect of polymer blending. The prepared membranes were tested for permeation of CO2 and CH4 at a feed pressure of 2 to 10 bar. PES-PSF membrane exhibits the separation properties identical to PES membrane. PES-PVAc blend membrane was found to be immiscible and high permeability was achieved while the selectivity was lost.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

172-175

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D. F. Sanders, Z. P. Smith, R. Guo, L. M. Robeson, J. E. McGrath, D. R. Paul, B. D. Freeman, Energy-efficient polymeric gas separation membranes for a sustainable future: A review, Polymer. 54 (2013) 4729-4761.

DOI: 10.1016/j.polymer.2013.05.075

Google Scholar

[2] R. Nasir, H. Mukhtar, Z. Man, D. F. Mohshim, Material Advancements in Fabrication of Mixed-Matrix Membranes, Chem. Eng. Technol. 36 (2013) 717-727.

DOI: 10.1002/ceat.201200734

Google Scholar

[3] D. F. Mohshim, H. Mukhtar, Z. Man, R. Nasir, Latest Development on Membrane Fabrication for Natural Gas Purification: A Review, J. Eng. 2013 (2013), 1-7.

DOI: 10.1155/2013/101746

Google Scholar

[4] H. A. Mannan, H. Mukhtar, T. Murugesan, R. Nasir, D. F. Mohshim, A. Mushtaq, Recent Applications of Polymer Blends in Gas Separation Membranes, Chem. Eng. Technol. 36 (2013) 1838-1846.

DOI: 10.1002/ceat.201300342

Google Scholar

[5] G. Kapantaidakis, S. Kaldis, X. Dabou, G. Sakellaropoulos, Gas permeation through PSF-PI miscible blend membranes, J. Membr. Sci. 110 (1996) 239-247.

DOI: 10.1016/0376-7388(95)00265-0

Google Scholar

[6] H. A. Mannan, H. Mukhtar, T. Murugesan, Preparation and characterization of newly developed polysulfone/polyethersulfone blend membrane for CO2 separation, Applied Mechanics & Materials [Accepted manuscript].

DOI: 10.4028/www.scientific.net/amm.699.325

Google Scholar

[7] S. Rafiq, Z. Man, A. Maulud, N. Muhammad, S. Maitra, Effect of varying solvents compositions on morphology and gas permeation properties on membranes blends for CO2 separation from natural gas, J. Membr. Sci. 378 (2011) 444-452.

DOI: 10.1016/j.memsci.2011.05.025

Google Scholar

[8] W. F. Yong, F. Y. Li, Y. C. Xiao, P. Li, K. P. Pramoda, Y. W. Tong, T. S. Chung, Molecular engineering of PIM-1/Matrimid blend membranes for gas separation, J. Membr. Sci. 407–408 (2012) 47-57.

DOI: 10.1016/j.memsci.2012.03.038

Google Scholar

[9] J. Ahmad, M. B. Hägg, Preparation and characterization of polyvinyl acetate/zeolite 4A mixed matrix membrane for gas separation, J. Membr. Sci. 427 (2013) 73-84.

DOI: 10.1016/j.memsci.2012.09.036

Google Scholar