Conversion of Biomass-Derived Oxygen-Containing Intermediates into Chemical Raw Materials with Zeolite

Takashi Goshima; Keisuke Ikeda; Kenta Fukudome; Kei Mizuta; Shuji Mitsuyoshi; Toshio Tsutsui

doi:10.4028/www.scientific.net/AMM.625.298

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 625Conversion of Biomass-Derived Oxygen-Containing...

Conversion of Biomass-Derived Oxygen-Containing Intermediates into Chemical Raw Materials with Zeolite

Abstract:

To establish a new production route of biomass-derived BTX and propylene, the catalytic conversion of oxygen-containing intermediates which are furfural, levulinic acid, acetic acid or butyric acid, obtained by hydrothermal reactions of bagasse or fermentation of molasses was investigated with zeolites, ZSM-5, SAPO-11 and SAPO-34. Levulinic acid and acetic acid were suitable for generating BTX with ZSM-5. On the other hand, the butyric acid was valuable for converting to chemical raw materials with ZSM-5. By using SAPO-11 as the catalyst, butyric acid converted to propylene at high yields. The yield for propylene was the maximum value 58.8C% at 723K, especially the ratio of propylene to gaseous hydrocarbon products increased up to 90.4C%.

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Periodical:

Applied Mechanics and Materials (Volume 625)

Pages:

298-305

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.625.298

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Online since:

September 2014

Authors:

Takashi Goshima, Keisuke Ikeda, Kenta Fukudome, Kei Mizuta, Shuji Mitsuyoshi, Toshio Tsutsui*

Keywords:

BTX, Chemicals from Biomass, Oxygen-Containing Intermediates, Propylene, Zeolite

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