Degradation Kinetic of Oxytetracycline Antibiotic inside UV Reactor in the Presence of H2O2

Article Preview

Abstract:

Oxytetracycline (OTC), a widely used of veterinary antibiotic, was degraded inside a UV/H2O2 system. Kinetic study was conducted at 30°C of temperature and pH 6.37, as suggested by the previous optimization experiment. About 250, 375 and 500 ppm initial OTC concentration were used for the kinetic studies, at H2O2 concentration of 0.116 M. The experimental data were plotted against the pseudo zero-th, first and second order of kinetic. Based on regression coefficient value, the data was well fitted with the pseudo first order of kinetic. The calculated value of kobs was 0.181 min-1.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

901-906

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] L. Dong, Y. Min, H. Jianying, Y. Zhang, H. Chang, F. Jin, Determination of penicillin G and its degradation products in a penicillin production wastewater treatment plant and the receiving river, Water Res., 42 (2008) 307-317.

DOI: 10.1016/j.watres.2007.07.016

Google Scholar

[2] W. Xu, G. Zhang, X. Li, S. Zou, P. Li, Z. Hu, J. Li, Occurrence and elimination of antibiotics at four sewage treatment plants in the Pearl River Delta (PRD), South China, Water Res., 41 (2007) 4526-4534.

DOI: 10.1016/j.watres.2007.06.023

Google Scholar

[3] M. Klavarioti, D. Mantzavinos, D. Kassinos, Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes, Environ. Int., 35 (2009) 402-417.

DOI: 10.1016/j.envint.2008.07.009

Google Scholar

[4] K. Kummere, Antibiotics in the aquatic environment, Chemosphere, 75 (2009) 417-434.

Google Scholar

[5] J.L. Martinez, Environmental pollution by antibiotics and by antibiotic resistance determinants, Environ. Poll. ¸ 157 (2009) 2893-2902.

DOI: 10.1016/j.envpol.2009.05.051

Google Scholar

[6] C. Garafalo, C. Viragnoli, G. Zandri, L. Aquilanti, D. Bordoni, A. Osimani, F. Clementi, F. Biavasco, Direct detection of antibiotics resistance genes in specimens of chicken and pork meat, Int. J. Food Microbiol, 113 (2007) 75-83.

DOI: 10.1016/j.ijfoodmicro.2006.07.015

Google Scholar

[7] A. Gulkowska, H.W. Leung, M.K. So, S. Taniyasu, N. Yamashita, Leo W.Y. Yeung, Bruce J. Richardson, A.P. Lei, J.P. Giesy, Paul K.S. Lam, Removal of antibiotics from wastewater by sewage treatment facilities in Hongkong and Shenzhen, China, Water Res., 42 (2008).

DOI: 10.1016/j.watres.2007.07.031

Google Scholar

[8] Y. Wang, J. B. Liang, T.C. Loh, Y. W. Ho, Use of Antibiotics in Pig and Poultry Farms in Malaysia, in: Conference on Sustainable Animal Agriculture for Developing Countries, 2009, http: /ibs. upm. edu. my/~saadc2009/slides/10-11-09-Corus1-1605-1620. pdf, retrieved on 20 January (2012).

Google Scholar

[9] M. O. Uslu, I. A. Balcioglu, Comparison of the ozonation and fenton process performance for the treatment of antibiotic containing manure, Sci. Tot. Environ., 407 (2009) 3450-3458.

DOI: 10.1016/j.scitotenv.2009.01.045

Google Scholar

[10] A. J. Bauger, J. Hensen, P. H. Krogh, Effects of antibiotics oxyteracycline and tylosin on soil fauna, Chemosphere, 40 (2000) 751-757.

DOI: 10.1016/s0045-6535(99)00449-x

Google Scholar

[11] Y. Wang, L. Wang, F. Li, J. Liang, Y. Li, J. Dai, T.C. Loh, Y.W. Ho, Effects of oxytetracycline and sulfachloropyridazine residues on the reductive activity of Shewanella decoloratis S12, J. Agric. Food Chem., 57 (2009) 878-5883.

DOI: 10.1021/jf900641e

Google Scholar

[12] O. A. Arikan, C. Rice, E. Codling, Occurence of antibiotics and hormones in a major agricultural watershed, Desalination, 226 (2008) 21-133.

DOI: 10.1016/j.desal.2007.01.238

Google Scholar

[13] I. R. Bautiz, R. F. P. Nogueira, Degradation of tetracycline by photo-Fenton process-Solar irradiation and matrix effect, J. Photochem. Photobiol. A, 187 (2007) 33-39.

Google Scholar

[14] K. Li, A. Yediler, M. Yang, S. Schulte-Hostede, M. H. Wong, Ozonation of oxytetrcycline and toxicological assessment of its oxidation by-products, Chemosphere, 72 (2008) 472-478.

DOI: 10.1016/j.chemosphere.2008.02.008

Google Scholar

[15] Y. Chen, C. Hu, J. Qu, M. Yang, Photodegradation of tetracycline and formation of reactive oxygen species in aqueous tetracycline under simulate sunglight irradiation, J. Photochem. Photobiol. A, 197 (2008) 81-87.

DOI: 10.1016/j.jphotochem.2007.12.007

Google Scholar

[16] J. Shaojun, Z. Shouron, Y. Daqiang, W. Lianhong, C. Liangyan, Aqueous oxytetracycline degradation and the toxicity change of degradation compounds in photoirradiation process, J. Environ. Sci., 20 (2008) 806-813.

DOI: 10.1016/s1001-0742(08)62130-0

Google Scholar

[17] R. Xuan, L. Arisi, Q. Wang, S. R. Yates, K. C. Biswas, Hydrolysis and photolysis of oxytetracycline in aqueous solution, J. Environ. Sci. Health B, 45 (2010) 73-81.

DOI: 10.1080/03601230903404556

Google Scholar

[18] C. Zhao, H. Deng, Y. Li, Z. Liu, Photodegradation of oxytetracycline in aqueous by 5A and 13X loaded with TiO2 under UV irradiation, J. Hazard. Mater., 176 (2010) 884-892.

DOI: 10.1016/j.jhazmat.2009.11.119

Google Scholar

[19] X. Wen, Y. Jia, J. Li, Enzymatic degradation of tetracycline and oxytetracycline by crude manganese peroxidise prepared from Phanerochaete chrysosporium, J. Hazard. Mater., 177 (2010) 924-928.

DOI: 10.1016/j.jhazmat.2010.01.005

Google Scholar

[20] S. Lin, W. Chen, C. Liu, Study on photochemical degradation of Oxytetracycline with UV-H2O2 process, in: 2nd Conference on Environmental Science and Information Application Technology, (2010) 24-27, doi: 10. 1109/ESIAT. 2010. 5568939.

DOI: 10.1109/esiat.2010.5568939

Google Scholar

[21] F. Yuan, C. Hu, X. Hu, D. Wei, Y. Chen, J. Qu, Photodegradation and toxicity changes of antibiotics in UV and UV/H2O2 process, J. Hazard. Mater., 185 (2011) 1256-1263.

DOI: 10.1016/j.jhazmat.2010.10.040

Google Scholar

[22] N. K. Shammas, L. K. Wang, Hazardous waste deep-well injection, In: L. K. Wang, N. K. Shammas, Y. T. Hung, Y. T., (Eds. ), Handbook of Advanced Industrial and Hazardous Waste Treatment, CRC Press, Florida, 2009, p.407.

DOI: 10.1201/9781420072228-c20

Google Scholar

[23] K. A. Loftin, C. D. Adams, M. T. Meyer, and R. Surampalli, Effects of ionic strenght, temperature, and pH on degradation of selected antibiotics, J. Environ. Qual., 37 (2008) 378-386.

DOI: 10.2134/jeq2007.0230

Google Scholar

[24] A. U. Rahmah, S. Harimurti, A. A. Omar, T. Murugesan, Optimization of Oxytetracycline Mineralization using Box-Behnken Experimental Design inside a UV/H2O2 system, J. App. Sci., 12 (2012) 1154-1159.

DOI: 10.3923/jas.2012.1154.1159

Google Scholar