Study on the Treatment of Oil-Produced Wastewater Using the Combined Processes Including Advanced Oxidation

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It is difficult to be degraded by biological process for some oil-produced wastewater containing high content of oil, salt, and COD. The combined process including advanced oxidation was adopted to handle it in this paper. The combined process including adsorption by furnace ash, coagulation by complex of ferro-aluminum salt, Fenton advanced oxidation, alkali out by NaOH and Fenton secondary oxidation was determined. Considering both the treatment effect and the cost, the optimizing process is as follows, the slurry of ferro-aluminum complex salt of 9% (m/m) was as a coagulant with a dosage of 0.8% (v/v); pH value of 3.2,Fe2+/H2O2 of 1/2.5(v:v) and 30 mmol/L dosage of FeSO4⋅7H2O was confirmed in advanced oxidation phase; NaOH was as precipitant with a dosage of 1%(m/m); Finally, after the secondary oxidation, the COD value greatly dropped from original 5 422 mg/L of raw oil-produced wastewater to 185.3 mg/L of effluent with a removal as high as 96.6%. It meets the national discharge standard on oil-produced wastewater. BOD5 / COD also rose from 0.23 to 0.39 which indicated an improved biochemical property.

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390-393

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September 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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