Effect of pH on Four Defluoridation Adsorbents under Natural High Fluoride Groundwater

Article Preview

Abstract:

Appropriate drinking water defluoridation technology is urgently needed in china, which has a wide fluoride-rich area. The adsorption defluoridation method in the industrial high fluoride wastewater treatment is generally considered to be efficient and economic. However, the practical application of the method is not ideal in obtaining drinking water defluoridation. Four representative adsorbents activated alumina, activated zeolite, hydroxyapatite and hydrous zirconium oxide have been tested in terms of defluoridation efficiency under natural high fluoride groundwater and compared to clarify existing problems of adsorption methods. Results show that pH significantly affected adsorption efficiency. The adsorbents have low adsorption capacity under natural high fluoride groundwater and can achieve good adsorption effect under acidic conditions. However, in adjusting the water to the appropriate pH range, the adsorption method loses its advantages of convenience and affordability. Therefore, any adsorbent should be tested with actual field waters before designing filed application systems. Further research is also warranted in evaluating the field performance and the economic acceptance of the proposed method.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

335-341

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J.H. Simons, Fluorine chemistry . Academic Press(1950).

Google Scholar

[2] US Public Health Service. Drinking water standards. PHS publication, 956, (1962).

Google Scholar

[3] WHO Expert Committee on Oral Health Status and Fluoride Use. Fluorides and oral health: report of a WHO expert committee on oral health status and fluoride use. World Health Organization (1994).

DOI: 10.5144/0256-4947.1995.297b

Google Scholar

[4] Z. Mandinic, M. Curcicb, B. Antonijevicb, M. Carevica, J. Mandica, D. Djukic-Cosicb and C.P. Lekicc, Fluoride in drinking water and dental fluorosis. Science of the total environment 408. 17 (2010): 3507-3512.

DOI: 10.1016/j.scitotenv.2010.04.029

Google Scholar

[5] J.J. Carrillo-Rivera, A. Cardona and W.M. Edmunds, Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potosi basin, Mexico. Journal of Hydrology. 261(2002).

DOI: 10.1016/s0022-1694(01)00566-2

Google Scholar

[6] National development and reform commission, ministry of water resources, the ministry of health, environmental protection department. 12th Five-year Plan on Rural Water Supply (2012).

Google Scholar

[7] M. Mohapatra, S. Anand, B.K. Mishra, D.E. Giles and P. Singh, Review of fluoride removal from drinking water. Journal of Environmental Management. 91. 1 (2009): 67–77.

DOI: 10.1016/j.jenvman.2009.08.015

Google Scholar

[8] Meenakshi and R.C. Maheshwari, Fluoride in drinking water and its removal. Journal of Hazardous Materials. 137. 1(2006): 456–463.

DOI: 10.1016/j.jhazmat.2006.02.024

Google Scholar

[9] W. Nigussie, F. Zewge and B.S. Chandravanshi, Removal of excess fluoride from water using waste residue from alum manufacturing process. Journal of Hazardous Materials. 147. 3(2007): 954-963.

DOI: 10.1016/j.jhazmat.2007.01.126

Google Scholar

[10] S.M. Maliyekkal, S. Shukla, L. Philip and I.M. Nambi, Enhanced fluoride removal from drinking water by magnesia-amended activated alumina granules. Chemical Engineering Journal. 140. 1-3. ( 2008), 183-192.

DOI: 10.1016/j.cej.2007.09.049

Google Scholar

[11] N. Chen, Z. Zhang, C. Feng, N. Sugiurab, M. Li and R. Chen, Fluoride removal from water by granular ceramic adsorption. Journal of Colloid and Interface Science. 348. 2(2010): 579-584.

DOI: 10.1016/j.jcis.2010.04.048

Google Scholar

[12] M. Karthikeyan, K.K.K. Satheesh and K.P. Elango, Batch sorption studies on the removal of fluoride ions from water using eco-friendly conducting polymer/bio-polymer composites. Desalination. 267. 1(2011): 49–56.

DOI: 10.1016/j.desal.2010.09.005

Google Scholar

[13] S. Ghorai and K.K. Pant, Investigations on the column performance of fluoride adsorption by activated alumina in a fixed-bed. Chemical Engineering Journal. 98. 1-2 ( 2004): 165-173.

DOI: 10.1016/j.cej.2003.07.003

Google Scholar

[14] Y.L. Tang, X.H. Guan, T.Z. Su, N.Y. Gaob and J.M. Wang, Fluoride adsorption onto activated alumina: Modeling the effects of pH and some competing ions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 337. 1-3 (2009): 33-38.

DOI: 10.1016/j.colsurfa.2008.11.027

Google Scholar

[15] A. Bhatnagar, E. Kumara and M. Sillanpaa, Fluoride removal from water by adsorption-A review. Chemical Engineering Journal. 171. 3 (2011): 811-840.

DOI: 10.1016/j.cej.2011.05.028

Google Scholar

[16] V. Ganvir and K. Das, Removal of fluoride from drinking water using aluminum hydroxide coated rice husk ash. Journal of Hazardous Materials. 185. 2-3(2011): 1287-1294.

DOI: 10.1016/j.jhazmat.2010.10.044

Google Scholar

[17] A.A. Moghaddam and E. Fijani, Distribution of fluoride in groundwater of Maku area, northwest of Iran. Environment Geology. 56. 2 (2008): 281-287.

DOI: 10.1007/s00254-007-1163-2

Google Scholar

[18] T. Rafique, S. Naseemb , T.H. Usmani, E. Bashirb, F.A. Khana and M.I. Bhangerc, Geochemical factors controlling the occurrence of high fluoride groundwater in the Nagar Parkar area, Sindh, Pakistan. Journal of Hazardous Materials. 171. 1-3 (2009).

DOI: 10.1016/j.jhazmat.2009.06.018

Google Scholar

[19] N.S. Rao, High-fluoride groundwater. Environmental Monitoring and Assessment. 176. 1-4 (2011): 637-645.

Google Scholar

[20] S. Battaleb-Looie, F. Moore , H. Jafari, G. Jacks and D. Ozsvath, Hydrogeochemical evolution of groundwaters with excess fluoride concentrations from Dashtestan, South of Iran. Environmental Earth Sciences. 67. 4 (2012): 1173-1182.

DOI: 10.1007/s12665-012-1560-z

Google Scholar

[21] C. Venkobachar, L. Iyengar, A.K. Mudgal, Household defluoridation of drinking water using activated alumina. 2nd International Workshop on Fluorosis Prevention and defluoridation of Water. (1997): 138-145.

Google Scholar

[22] R. Buamah, R.A. Mensah and A. Salifu, Adsorption of fluoride from aqueous solution using low cost adsorbent. Water Science and Technology: Water Supply. 13. 2(2013): 238–248.

DOI: 10.2166/ws.2013.016

Google Scholar

[23] W. Ma, Chemistry and solid water interface adsorption technology. Beijing, Metallurgical Industry Press (2011): pp.203-204.

Google Scholar

[24] C.R.N. Rao and J. Karthikeyan, Removal of Fluoride from Water by Adsorption onto Lanthanum Oxide. Water Air Soil Pollut. 223. 3(2012): 1101-1114.

DOI: 10.1007/s11270-011-0928-0

Google Scholar

[25] Jae-Hyun. Kim, Chang-Gu. Lee, Jeong-Ann. Park, In-Kyu. J Kang, Seo-Young. Yoon and Song-Bae. Kim. Fluoride removal using calcined Mg/Al layered double hydroxides at high fluoride concentrations. Water Science and Technology, Water Supply. 13. 2(2013).

DOI: 10.2166/ws.2013.001

Google Scholar