The Effect of Citric Acid on the Mechanical Properties of Thermoplastic Tapioca Starch/High Density Polyethylene/Natural Rubber Blends

Article Preview

Abstract:

Effects of citric acid on the mechanical properties of thermoplastic tapioca starch/high density polyethylene/natural rubber (HDPE/NR/TPS) blends were investigated. The ratio between HDPE/NR was fixed at 70/30 and used as a matrix system. TPS loadings with and without modification with citric acid (CA) were varied from 0% to 30wt%. Mechanical and physical properties of blends were evaluated as a function of TPS loadings modified with and without CA. The tensile strength, Young’s modulus and elongation at break were found to decrease with increasing TPS content. However an improvement in the tensile strength for TPS modified with CA at 5%, 10% and 20% TPS loadings was observed. The degree of TPS adhesion and dispersion in HDPE/NR blends were determined by scanning electron microscope (SEM).Keywords; HDPE/NR/TPS, citric acid, tensile properties, morphology.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

292-299

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Averous. L, Moroa. L, Dole. P, & Fringant.C. 2000. Properties of thermoplastic blends: starch–polycaprolactone. Polymer. 41: 4157–4167.

DOI: 10.1016/s0032-3861(99)00636-9

Google Scholar

[2] Bikiaris. D, Prinos. J, Koutsopoulos. K, Vouroutzis. N, Pavlidou. E, Frangi. N & Panayiotou.C. 1998. LDPE/plasticized starch blends containing PE-g-MA copolymer as compatibilizer. Polymer Degradation and Stability. 59: 287-291.

DOI: 10.1016/s0141-3910(97)00126-2

Google Scholar

[3] Carvalho. A.J. F, Marcia. D, Zambon A. Curvelo. A & Gandini. A. 2005. Thermoplastic starch modification during melt processing: Hydrolysis catalyzed by carboxylic acids. Carbohydrate Polymers. 62: 387–390.

DOI: 10.1016/j.carbpol.2005.08.025

Google Scholar

[4] Chandra. R & Rustgi. R. 1997. Biodedegradation of maleated linear low-density polyethylene and starch blends. Polymer Degradation and Stability. 56: 185-202.

DOI: 10.1016/s0141-3910(96)00212-1

Google Scholar

[5] Comyn. J. 1997. Chemistry of Adhesives which Harden without Chemical reaction. In Adhesion Science. The royal Society of Chemistry, Thomas Graham House. United kingdom.

DOI: 10.1039/9781847550064-00054

Google Scholar

[6] Davies, G., & Henrissat, B. 1995 Structures and mechanisms of glycosyl hydrolyses. Structure, 3, 853-859.

Google Scholar

[7] Fang, J. M., Fowler, P. A., Tomkinson, J. & Hill, C.A.S. 2002 The preparation and characterization of a series of chemically modified potato starches. Carbohydrate Polymers, 47, 245-252.

DOI: 10.1016/s0144-8617(01)00187-4

Google Scholar

[8] Hirashima. M, Takahashi. R & Nishinari. K. 2005. Effects of adding acids before and after gelatinization on the viscoelasticity of cornstarch pastes. Food Hydrocolloids. 19: 909–914.

DOI: 10.1016/j.foodhyd.2004.12.004

Google Scholar

[9] Jayasekara, R., Harding, I., Bowater, I., Christie, G. B. Y. & Lonergan, G. T. 2004 Preparation, surface modification and characterisation of solution cast starch. PVA blended films. Polymer Testing, 23, 17–27.

DOI: 10.1016/s0142-9418(03)00049-7

Google Scholar

[10] Ning, W., Jiugao, Y., Xiaofei, M., & Ying, W. 2007 The influence of citric acid on the properties of thermoplastic starch/linear low-density polyethylene blends. Carbohydrate Polymers, 67, 446–453.

DOI: 10.1016/j.carbpol.2006.06.014

Google Scholar

[11] Raquez, J., Nabar, Y., Srinivasan, M., Shin, B., Narayan, R., & Dubois, P., 2008 Maleated thermoplastic starch by reactive extrusion. Carbohydrate Polymers, 74, 159-169.

DOI: 10.1016/j.carbpol.2008.01.027

Google Scholar

[12] Ramis. X, Cadenatoa. A, Sallaa. J. M, Moranchoa. J. M, Contat. A.V. L, & A. Ribes. A. 2004. Thermal degradation of polypropylene/starch-based materials with enhanced biodegradability. Polymer Degradation and Stability. 86: 483-491.

DOI: 10.1016/j.polymdegradstab.2004.05.021

Google Scholar

[13] Shi. R, Zhang. Z, Liu. Q, Han. Y, Zhang. L, Chen. D & Tian. W. 2007. Characterization of citric acid/glycerol co-plasticized thermoplastic starch prepared by melt blending. Carbohydrate Polymers. 69: 748–755.

DOI: 10.1016/j.carbpol.2007.02.010

Google Scholar

[14] Singh, J., Kaur, L., & McCarthy, O. J. 2007 Factors influencing the physico-chemical, morphological, thermal and rheological properties of some chemically modified starches for food applications—A review. Food Hydrocolloids, 21, 1–22.

DOI: 10.1016/j.foodhyd.2006.02.006

Google Scholar

[15] Soest. J.J.G. V, Benes. K, Wit. D & Vliegenthart. J.F.G. 1996. The influence of starch molecular mass on the properties of extruded thermoplastic starch. Polymer. 37(16): 3543-3552.

DOI: 10.1016/0032-3861(96)00165-6

Google Scholar

[16] Ning. W, Jiugao. Y, Xiaofei. M & Ying. M. 2007. The influence of citric acid on the properties of thermoplasticstarch/linear low-density polyethylene blends. Carbohydrate Polymers. 67: 446–453.

DOI: 10.1016/j.carbpol.2006.06.014

Google Scholar

[17] Xie, X. J., & Liu, Q. 2004 Development and physicochemical characterization of new resistant citrate starch from different corn starches. Starch/Starke, 56, 364–370.

DOI: 10.1002/star.200300261

Google Scholar