Pyrolysis of Empty Fruit Bunch (EFB) in a Vertical Fixed Bed Reactor

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Uncontrolled uses of fossil fuels lead to serious energy problems and since Malaysia is one of the largest producers of palm oil in the world, it has caused a lot of waste such as empty fruit bunches (EFB) which can actually be converted into renewable energy via pyrolysis. In this work, firstly the characterizations of the EFB were analyzed such as elemental, proximate and component analysis. The pyrolysis experiment of empty fruit bunch using vertical fixed-bed reactor was conducted at different pyrolysis temperature range from 300 - 600 °C and the particle size of EFB was also varied from 125-250 μm with constant nitrogen flow rate of 100 cm3/min, heating rate of 30 °C/min, and 30 minutes hold time. For the effect of temperature, the optimum pyrolysis temperature was 500 °C to produce maximum yield of bio-oil which is 39.2 wt. % while 46.13 wt. % is the highest bio-oil yield produced at size of 500-710 μm for the effect of particle size. The analysis on bio-oil was conducted by using Fourier Transform Infrared (FTIR) with the results shows for the presents of phenol/alcohol group, ketones and C-O bond. The bio-oil obtained is in the acidic condition with pH 3.5.

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228-231

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November 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Al-Kassir, A. Ganan, J. Gonzales, C. M. Gonzales, J. F. Mangut, V. Ramoro, A. Roman, S. and Sabio, E. Thermogravimetric study of the pyrolysis of biomass residue from tomato processing industry, Journal of Fuel Process Technology. 87(2006).

DOI: 10.1016/j.fuproc.2005.08.006

Google Scholar

[2] Li, S. Xu, S. Liu, S. Yang, C. and Lu, Q. Fast pyrolysis of biomass in free-fall reactor for hydrogen-rich gas, Journal of Fuel Processing Technology. 85(2004) 1201-1211.

DOI: 10.1016/j.fuproc.2003.11.043

Google Scholar

[3] Abdullah, N. and Gerhauser, H. Bio-oil derived from empty fruit bunches, Journal of Fuel. 87 (2008) 2606-2613.

DOI: 10.1016/j.fuel.2008.02.011

Google Scholar

[4] Slopiecka, K. Bartocci, P. and Fantozzi, F. Thermogravimetric analysis and kinetic study of poplar wood pyrolysis, Journal of Applied Energy. 97(2012) 491-497.

DOI: 10.1016/j.apenergy.2011.12.056

Google Scholar

[5] Blake, F. S. R. and Ramsden, M. J. A kinetic study of the acetylation of cellulose, hemicelluloses and lignin components in wood, Journal of Wood Science and Technology. 31 (1997) 45-50.

DOI: 10.1007/bf00705699

Google Scholar

[6] Acikgoz, C. Kockar, O. M. and Onay, O. Fast pyrolysis of linseed: product yields and compositions, Journal of Analytical and Applied Pyrolysis. 71 (2004) 417-429.

DOI: 10.1016/s0165-2370(03)00124-4

Google Scholar

[7] Ozbay, N. Putun, A. E. Uzun, B. B. And Varol, E. A. Characterization of bio-oil obtained from fruit pulp pyrolysis, Journal of energy. 33 ( 2008) 1233-1240.

DOI: 10.1016/j.energy.2008.04.006

Google Scholar

[8] Azduwin, K. Ridzuan, M.J.M. Hafis, S.M. and Amran, T.A. Slow Pyrolysis Of Imperata Cylindrica in a Fixed Bed Reactor, International Journal of Biological, Ecological and Environmental Sciences. 1(5) (2012) 176-180.

Google Scholar