Copolymerization of Propylene Oxide and Carbon Oxide Catalyzed by Nano SalenCoCl Complex

Jing Tian; Sai Dan Zhang; Qing Zhang; Ming Zhe Liu; Yan Guo Wang

doi:10.4028/www.scientific.net/AMM.703.17

Paper Titles

Preface and Conference Organization

Properties of a Solid–Solid Phase Change Material PAN/SA-LA/ZMS
p.3

Research on Microstructure and Mechanical Properties of B₄C/Al Composites by Liquid Mental Mixing
p.9

Copolymerization of Propylene Oxide and Carbon Oxide Catalyzed by Nano SalenCoCl Complex
p.17

Corrosion of High Zn Content Al-Zn-Mg-Cu Alloy in 3.5 wt.% NaCl Solution
p.21

Crystal Structure and Antioxidant Activity of 6-Gingerol Oxime
p.29

Evaluation of Binary System (NaI-Na₃PO₄) Solid Electrolyte and Performance of Sodium Battery
p.33

Fabrication Technology Study of Thermal Isolation Structure on Chip
p.41

Flow Behavior of Composites of PA6/Kaolin Nanoparticles
p.45

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 703Copolymerization of Propylene Oxide and Carbon...

Copolymerization of Propylene Oxide and Carbon Oxide Catalyzed by Nano SalenCoCl Complex

Abstract:

In this investigation, nanoSchiff bases Cobaltic complex was synthesized and used as the initiator in the copolymerization of carbon oxide and propylene oxide (PO). The nanoCobaltic complex was characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The influences of different factors, including reaction time, reaction temperature, and pressure of CO₂ on the synthesis of polycarbonate were described. The results show that nanoCobaltic complex could be successfully applied in the copolymerization of CO₂ and PO. The optimum conditions of the polymerization, which include CO₂pressure of 30 bar, reaction temperature of 80 °C, and reaction time of 3 hours.