Synthesis of Novel Monomer with Quinoxaline Derivatives

Pei Lin Zhang; Tao Hu; Xiao Xia Sun

doi:10.4028/www.scientific.net/AMM.707.32

Paper Titles

Preparation and Characterization of N-Octyl Pyridine Tetrafluoroborate
p.16

Determination Content of N-Octyl Pyridine Tetrafluoroborate in Water Using UV-Spectrum
p.20

UV-Spectrum Analysis of N-Octyl Pyridine Tetrafluoroborate in Ethanol
p.24

Synthesis of a New Monomer: 4,7-bis(5-phenylthiophen-2-yl)benzo[c][1,2,5]selenadiazole
p.28

Synthesis of Novel Monomer with Quinoxaline Derivatives
p.32

Synthesis and Photochromism Studies of 1-(2-n-butyl-3-benzothienyl)-2-[2-methyl-5-phenyl-3-thienyl] Perfluorocyclopentene
p.36

Synthesis and Photochromism Studies of 1,2-bis[2-methyl-5-(4-bromomethylphenyl)-3-thienyl] Perfluorocyclopentene
p.40

Synthesis and Properties of [1-(3,5-dimethyl-4-iodoisoxazole)-2-(2-methyl-(5-ethynyl)trimethylsilane-3-thienyl)perfluorocyclopentene
p.44

Synthesis and Photochromic Properties of Diarylethene 1-[2-methyl-5-(4-trifluoromethylphenyl)-3-thienyl]-2-[2-methyl-5-(3-fluoro-4-chloro)phenyl-3-thienyl]perfluorocyclopentene
p.48

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 707Synthesis of Novel Monomer with Quinoxaline...

Synthesis of Novel Monomer with Quinoxaline Derivatives

Abstract:

Novel rigid dendrimer containing cross-conjugated units are synthesized from the coupling of 2-thiophene-based dendron with 5,8-dibromo-2,3-dithienylquinoxaline. The new monomer 2,3,5,8-tetrathienylquinoxaline has been successfully synthesized with moderate yield over five steps. The structure of the monomer was determined by H-NMR and C-NMR technologies. And the optical characterization of the monomer was also determined by the UV-vis and fluorescence spectrometer. The monomer has a high absorption peak at 206 nm and high emission peak at 430 nm. The monomer was freely soluble in variety of organic solvent, such as chloroform and acetonitrile.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 707)

Pages:

32-35

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.707.32

Citation:

Cite this paper

Online since:

December 2014

Authors:

Pei Lin Zhang, Tao Hu, Xiao Xia Sun*

Keywords:

Donor-Acceptor, Light-Emitting Material, Organic Molecule

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] JieFeng, H.; Wei, Y.; BaoFeng, Z.; Yang, L.; LiangMing, Y.; EnWei, Z.; LinYi. B.; Jian. Z.; HongBin. W.; WeiHua. T.; Polym. Chem., 10 (2013) 1039.

Google Scholar

[2] Yi, Z.; Lei, G.; Chang, H.; QingJiang, S.; YongFang, L.; Polym. Chem., 4 (2013) 1474.

Google Scholar

[3] Abay, G.; Wendimagegn Mammo, L. Mattias Andersson, Shimelis Admassie, FengLing, Zhang, Mats R. Andersson, Olle I. Adv. Funct. Mater., 17(2007) 3836.

DOI: 10.1002/adfm.200700441

Google Scholar

[4] Inganas. O.; Zhang. F.; Tvingstedt. K.; Andersson. L. M.; Hellstrom. S.; Andersson. M. R. Adv. Mater., 22 (2010) E100.

Google Scholar

[5] Yamamoto, T.; Zhou, Z.; Kanbara, T.; Shimura, M.; Kizu, K.; Maruyama, T.; Nakamura, Y.; Fukuda, T.; Lee, B. -L.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K.; Sasaki, S.; J Am Chem. Soc., 118 (1996) 10389.

DOI: 10.1021/ja961550t

Google Scholar

[6] Qiang, P.; Jun, X.; WenXu, Z. Polymer Chemistry, 47(2009) 3399.

Google Scholar