Study on Properties of Epoxy Resins Modified by Nano-Silica

Article Preview

Abstract:

Organic precursor of EP/PU was prepared by epoxy resin which was polyurethane toughened, and then modified epoxy resin adhesive was synthesized using nano-silica as modifier. Microstructure of composite materials was observed by scanning electron microscopy (SEM), the results showed that the inorganic phase had good compatibility in polymer matrix, and polyurethane in epoxy resin have formed the "island structure". The mechanical properties, thermal stability and dielectric loss, dielectric constant of composites were investigated. The results indicated that doping of appropriate amount of nano-silica could improve mechanical property, shear strength and impact strength of 2wt% SiO2/EP-PU were increased 173% and 106.67%, than that of pre-doping of composite, respectively. Thermal decomposition temperature (Td) was increased, Td of 2wt%SiO2/EP-PU was increased 8.1°C than that of pre-doped of material. Dielectric constant (ε) was as follows: was decreased with the increase of frequency, but increased with the increase of inorganic component, dielectric loss (tanδ) was increased with the increase of frequency and inorganic doping.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1005-1008

Citation:

Online since:

July 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Kung-Chin Chang, Chang-Yu Lin, Hui-Fen Lin, etc. Thermally and Mechanically Enhanced Epoxy Resin-Silica Hybrid Materials Containing Primary Amine-Modified Silica Nanoparticles[J]. Journal of Applied Polymer Science, 2008, 108, 1629-1635.

DOI: 10.1002/app.27559

Google Scholar

[2] Shiqiang Deng, Lin Y, Klaus Friedrich. Fracture behaviours of epoxy nano- composites with nano-silica at low and elevated temperature [J]. J Mater Sci. 2007, 42: 2766-2774.

DOI: 10.1007/s10853-006-1420-x

Google Scholar

[3] Barabanova, A.I. Shevnin, P. L. Nanocomposites based on epoxy resin and silicon dioxide particles [J]. Polymer, 2008, 50: 808-819.

DOI: 10.1134/s0965545x08070110

Google Scholar

[4] Wu C S, Liu Y L, Chiu Y S. Epoxy resins possessing flame retardant elements from silicon incorporated epoxy compounds cured with phosphorus or nitrogen containing curing agents [J]. Polymer, 2002, 43: 4277-4284.

DOI: 10.1016/s0032-3861(02)00234-3

Google Scholar

[5] Hai-liang Zhang, Cai-xing Zhao, Xia-yu Wang. Preparation and characterization of epoxy-silica hybrid materials by the sol-gel process [J]. Journal of Materials Science. 2005, 40: 1079-1085.

DOI: 10.1007/s10853-005-6920-6

Google Scholar

[6] Gu Jun-Wei, Zhang Qiu-Yu, et al. Study on preparation of SiO2/epoxy resin hybrid materials by means of sol-gel [J]. Polymer, 2007, 46: 1129-1134.

Google Scholar