Improved Ghost Plating of Light-Induced Plating on Crystalline Silicon Solar Cells by SiO2/SiN Selective Etching

Article Preview

Abstract:

In this paper, the ghost plating problems of crystalline silicon solar cells is studied in theory and experiment. After laser doping process, a pretreatment process is needed to remove SiO2 in the heavy doping area and keep SiN mask simultaneously by using chemical solution containing HF. Otherwise, the unexpected non-heavy-doping area would be plated with silver, resulting in the ghost plating problems. The mechanism of HF etching SiO2 and SiN is analyzed and the feasibility of selective etching is discussed. By changing the main aspects of affecting the etching rate, the ghost plating of crystalline silicon solar cells is improved.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2290-2293

Citation:

Online since:

July 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S.R. Wenham, C.B. Honsberg, M.A. Green, Buried contact silicon solar cells, in: 7th International Photovoltaic Science and Engineering Conference, Tokyo, Japan, 1993, pp.83-86.

Google Scholar

[2] D. Knotter, Etching mechanism of vitreous silicon dioxide in HF-based solutions, J. Am. Chem. Soc, 122 (2000) 4345-4351.

DOI: 10.1021/ja993803z

Google Scholar

[3] W. Claassen, W. Valkenburg, M. Willemsen, W. vd Wijgert, Influence of deposition temperature, gas pressure, gas phase composition, and RF frequency on composition and mechanical stress of plasma silicon nitride layers, J. Electrochem. Soc., 132 (1985).

DOI: 10.1149/1.2113980

Google Scholar

[4] K. Allaert, A. Van Calster, H. Loos, A. Lequesne, A comparison between silicon nitride films made by PCVD of NZSiH4/Ar and NzSiH4/He, J. Electrochem. Soc., 132 (1985) 1763.

DOI: 10.1149/1.2114207

Google Scholar

[5] D.M. Knotter, T.J.J. Denteneer, Etching mechanism of silicon nitride in HF-based solutions, J. Electrochem. Soc., 148 (2001) 43-46.

DOI: 10.1149/1.1348262

Google Scholar

[6] J. Guo, J. Cotter, Metallization improvement on fabrication of interdigitated backside and double sided buried contact solar cells, Sol. Energy Mater. Sol. Cells, 86 (2005) 485-498.

DOI: 10.1016/j.solmat.2004.09.001

Google Scholar

[7] C. Deckert, Etching of CVD Si 3 N 4 in acidic fluoride media, J. Electrochem. Soc., 125 (1978) 320.

DOI: 10.1149/1.2131436

Google Scholar