Effect of Glycerol Carbonate as Plasticizer on P(AN-MMA) Polymer Electrolyte

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Abstract:

A kind of new plasticizer glycerol carbonate (GC) was synthesized. The poly (acrylonitrile-methyl methacrylate) (P(AN-MMA)) was prepared by bulk polymerization. During the polymerization, glycerol carbonate with 1M lithium perchlorate (LiClO4) was added to (P(AN-MMA)) to form the gel electrolyte. The effect of the plasticizer on the conductivity of the copolymer electrolyte was studied. The ionic conductivity was found to be 3.3 × 10-4 S·cm-1 at room temperature via AC impedance measurement.

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2658-2662

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January 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Feuillade, G.; Perche, P. J. Appl. Electrochem. 1975, 5, 63.

Google Scholar

[2] Abraham, K.M.; Alamgir, M. J. Electrochem. Soc. 1990, 37, 1657.

Google Scholar

[3] Sivakumar, M,; Subadevi, R.; Rajendran, S.; Wu, H. -C.; Wu, N-L. Eur. Polym. J. 2007, 43, 4466.

Google Scholar

[4] Stephan, A. M. Eur. Polym. J. 2006, 42, 21.

Google Scholar

[5] Reiter, J.; krejza, O.; Sedlaříková, M. Sol. Energ. Mat. Sol. C. 2009, 93, 249.

Google Scholar

[6] Sharma, J.P.; Sekhon, S,S. Mate. . Sci. Eng. B 2006, 129, 104.

Google Scholar

[7] Jo, C.; Fu, J.; Naguib, H.E. Polymer 2005, 46, 11896.

Google Scholar

[8] Agnihotry, S. A,; Ahmad, Shahzada; Gupta, D.; Ahmad Sharif. Electrochim. Acta. 2004, 49, 2343.

Google Scholar

[9] Pu,W.; He,X.; Wang,L.; Tian, Z.; Jiang, C.; Wan, C. J. Membr. Sci. 2006, 280, 6.

Google Scholar

[10] Lee K.H.; Lee Y.G.; Park, J.K.; Seung D.Y. Solid State Ion. 2000, 133, 257.

Google Scholar

[11] Zhang, S.S.; Xu, K.; Jow, T.R. Solid State Ioni. 2003, 158 , 375.

Google Scholar

[12] Kim D.W.; Ko,J.M.; Chun, J.H. J. Power Sources 2001, 93 , 151.

Google Scholar

[13] Zhang S.S.; Jow T.R. J. Power Sources 2002, 109, 422.

Google Scholar

[14] Jeong Y.B., Kim D.W. J. Power Sources 2004, 128 , 256.

Google Scholar

[15] Wu, G.; Yang, H.Y.; Chen, H.Z.; Yuan,F.; Yang, L.G.; Wang, M.; Fu,R.J. Mater. Chem. Phys. 2007, 104 , 284.

Google Scholar

[16] Lelovský, M.; Kaszonyi, A. 44th International Petroleum Conference, Bratislava, Slovak Republic, 2009, September 21.

Google Scholar

[17] Wang, Z.; Huang, B.; Huang, H.; Xue ,R.; Chen, L.; Wang, F.A. J. Electrochem. Soc. 1996, 143, 1510.

Google Scholar

[18] Tsuchida, E.; Ohno, H.; Tsuchida, E. Electrochim Acta 1983, 28, 591.

Google Scholar

[19] Amal, A.K.; Diogo, V.; César, O. A.; Edson, R. L.; Michel, A. A; Agnieszka, P. Ionics 2001, 16, 13.

Google Scholar