Electrical Property of Methylcellulose/Chitosan-NH4NO3-EC Plasticized Polymer Electrolyte

N.L.M. Zazuli; Azwani Sofia Ahmad Khiar

doi:10.4028/www.scientific.net/AMM.719-720.82

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 719-720Electrical Property of...

Electrical Property of Methylcellulose/Chitosan-NH₄NO₃-EC Plasticized Polymer Electrolyte

Abstract:

Polymer electrolytes blends of methylcellulose (MC)/chitosan-ammonium triflate (NH₄CF₃SO₃) plasticized with Ethylene Carbonate (EC) were prepared by solution-casting technique. The effect on electrical property was investigated by impedance spectroscopy. Sample with 45 wt% of EC exhibit the highest room temperature conductivity of 2.16 × 10^-4 Scm^-1. Dielectric data were analyzed for the sample with the highest conductivity.

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Periodical:

Applied Mechanics and Materials (Volumes 719-720)

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82-86

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https://doi.org/10.4028/www.scientific.net/AMM.719-720.82

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Online since:

January 2015

Authors:

N.L.M. Zazuli, Azwani Sofia Ahmad Khiar*

Keywords:

Chitosan, Methylcellulose, Plasticizer, Polymer Electrolyte

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References

[1] V. Di Noto, S. Lavina, G.A. Giffin, E. Negro, B. Scrosati, Polymer Electrolytes: Present, Past And Future, Electrochim. Acta 57 (2011) 4-13.

DOI: 10.1016/j.electacta.2011.08.048

Google Scholar

[2] S. Ahmad, Polymer Electrolytes: Characteristics And Peculiarities, Ionics 15 (2009) 309-321.

Google Scholar

[3] M. Kumar and S. S. Sekhon, Role of Plasticizer's Dielectric Constant on Conductivity Modification of PEO–NH4F Polymer Electrolytes, Eur. Polym. J. 38. (2002) 1297-1304.

DOI: 10.1016/s0014-3057(01)00310-x

Google Scholar

[4] D.K. Pradhan, K. Samantaray, N.P. Choudhary, A.K. Thakur, Effect of Plasticizer on Structure-Property Relationship in Composite Polymer Electrolytes, J. Power Sources 13. (2005) 384-393.

DOI: 10.1016/j.jpowsour.2004.05.050

Google Scholar

[5] A. Bhide, and K. Hariharan, Ionic Transport Studies on (PEO)6: NaPO3 Polymer Electrolyte Plasticized with PEG400, Eur. Polym. J. 43 (2007) 4253-4270.

DOI: 10.1016/j.eurpolymj.2007.07.038

Google Scholar

[6] T. Kuila, H. Acharya, S.K. Srivastava, B.K. Samantaray and S. Kureti, Enhancing the Ionic Conductivity of PEO Based Plasticized Composite Polymer Electrolyte by LaMnO3 nanofiller, Mat Sci Eng B 131 (2007) 217-224.

DOI: 10.1016/j.mseb.2006.11.023

Google Scholar

[7] M. Egashira, H. Todo, N. Yoshimoto, and M. Morita, Lithium Ion Conduction in Ionic Liquid-Based Gel Polymer Electrolyte. J. Power Sources, 178 (2008) 729- 735.

DOI: 10.1016/j.jpowsour.2007.10.063

Google Scholar

[8] K.Z. Hamdan, A.S.A. Khiar, Conductivity and Dielectric Studies of MethylcelluloseChitosan-NH4CF3SO3 Polymer Electrolyte. Key Eng. Mat 594-595 (2013) 818-822.

Google Scholar

[9] R.G. Linford, Electrical and Electrochemical Properties of Ion Conducting Polymers, in: B. Scrosati (Ed. ), Applications of Electroactive Polymers, Chapman and Hall, London, 1993, pp.1-28.

DOI: 10.1007/978-94-011-1568-1_1

Google Scholar

[10] C.S. Ramya, S. Selvasekarapandian, T. Savitha and G. Hirankumar, Vibrational and Impedance Spectroscopic Study on PVP–NH4SCN Based Polymer Electrolytes, Physica B 393. (2007) 11-17.

DOI: 10.1016/j.physb.2006.11.021

Google Scholar

[11] A.S. Samsudin, M.I.N. Isa, Structural and Ionic Transport Study on CMC Doped NH4Br: New Type of Biopolymer electrolytes. J. Appl. Sci, 12 (2012) 174-179.

DOI: 10.3923/jas.2012.174.179

Google Scholar

[12] H.J. Woo, S.R. Majid, A.K. Arof, Effect of Ethylene Carbonate on Proton Conducting Polymer Electrolyte Based on Poly(Ε-Caprolactone) (PCL), Solid State Ionics 252 (2013) 102–108.

DOI: 10.1016/j.ssi.2013.07.005

Google Scholar

[13] A.S.A. Khiar, R. Puteh, A.K. Arof, Conductivities Studies of a Chitosan-Based Polymer Electrolyte, Physica B 373 (2006) 23-27.

DOI: 10.1016/j.physb.2005.10.104

Google Scholar

[14] D.K. Pradhan, R.N.P. Choudhary, B.K. Samantaray. Studies of Dielectric and Electrical Properties of Plasticized Polymer Nanocomposite Electrolytes, Mat. Chem. Phys. 115 (2009) 557–561.

DOI: 10.1016/j.matchemphys.2009.01.008

Google Scholar