Comparison of Glass Transition Temperature Values of Composite Polymer Obtained by TMA and DSC

Article Preview

Abstract:

In recent years a number of studies were conducted in order to obtain polymer composites with superior performance when compared to the metallic alloys. However, these new materials must meet a series of rigid project requirements. One way to evaluate the polymer composites is through their transition temperatures, especially the glass transition temperature (Tg). It is possible to evaluate the Tg of a polymeric material through the study of changes in dimensions of a sample as a function of temperature. These measurements can be made on an equipment of thermomechanical analysis (TMA), however, despite great sensitivity, this technique is basically unknown by most users when compared to others such as DSC or DMA. Even with different technical principles of operation, the results show similarity. Thus, this study aims to compare the results of Tg polymer composites obtained via TMA with those obtained from DSC curves in epoxy resin/carbon fiber laminates.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

91-95

Citation:

Online since:

January 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] E. C. Ortiz, Tese de Mestrado, Instituto de Engenharia Aeronáutica e Mecânica, ITA, (2008).

Google Scholar

[2] MAZUR, R. L. Obtenção e caracterização de compósitos de fibras de carbono/PEKK com aplicações aeronáuticas. 2010. 140f. Tese (Doutorado em Engenharia Mecânica) – Faculdade de Engenharia do Campus de Guaratinguetá; Universidade Estadual Paulista, Guaratinguetá, (2010).

DOI: 10.3934/jimo.2010.6.315

Google Scholar

[3] BANDEIRA, C. F.; PEREIRA, A. C.; BOTELHO, E. C.; COSTA, M. L. Comparação dos valores de transição vítrea de compósitos poliméricos obtidos via TMA e DSC In: CONGRESSO BRASILEIRO DE POLÍMEROS, 11., 2011, Campos do Jordão, Anais… Campos do Jordão: CBPol, 2011. 1 CD-ROM.

DOI: 10.47749/t/unicamp.2019.1089160

Google Scholar

[4] MANO, E. B. B; MENDES, L. C. Introdução a polímeros. 2. ed. São Paulo: Edgard Blucher, 1999. 208p.

Google Scholar

[5] COSTA, M. L. Estabelecimento da parâmetros de processamento de compósitos estruturais via análises térmicas e viscosimétricas. 1998. 162f. Dissertação (Mestrado em Ciência) - Instituto Tecnológico de Aeronáutica, São José dos Campos, (1998).

DOI: 10.14393/19834071.2014.26671

Google Scholar

[6] PRIME, R. B. Thermosets in thermal characterization of polymeric materials. London: Academic Press, cap. 5, pp.435-569, (1981).

DOI: 10.1016/b978-0-12-703780-6.50010-9

Google Scholar

[7] COSTA NETO, P. L. O. Estatística. 2. ed. São Paulo: Edgard Blücher, 2002. 266p.

Google Scholar

[8] AMERICAN SOCIETY FOR TESTING AND MATERIAL. ASTM D 3418: standard test method for transition and enthalpies of fusion ad crystallization of polymers by differential scanning calorimetry. U.S., (2008).

DOI: 10.1520/d3418-99

Google Scholar

[9] AMERICAN SOCIETY FOR TESTING AND MATERIAL. ASTM E 1545: standard test method for Assignment of the Glass Transition Temperature by Thermomechanical Analysis. U.S., (2011).

Google Scholar