Comparison between Commercial and Synthesized Hyperbranched Polyesters Regarding Fracture Toughness of Epoxy Matrix

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A hyperbranched poly (butylene adipate) (HPBA) polymer was compared with a commercial dendritic polyol (Boltorn H311) as toughening agent for a commercial one-part epoxy resin, Cycom 890 RTM. Both modifiers were added in a weight percentage 1, 3, 5 and 10 %. Blends obtained were characterized through DMA and impact resistance (KIC). SEM morphology were also evaluated. The toughness improvement was achieved without substantial impairment on thermomechanical properties. Fractography analysis has evidenced the fracture standard changing from brittle to ductile by modifiers addition.

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110-113

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January 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] C. Wu, W. Xu, Atomistic simulation study of absordeb water influence on structure and properties of crosslinked epoxy resin, Polymer. 48 (2007) 5440-5448.

DOI: 10.1016/j.polymer.2007.06.038

Google Scholar

[2] M. Flores, X. F. -Francos, F. Ferrando, X. Ramis, A. Serra, Efficient impact resistance improvement of epoxy thermosets by adding hyperbranched polyesters parttialy modified with undecenoyl chain, Polymer. 53 (2012) 5232-5241.

DOI: 10.1016/j.polymer.2012.09.031

Google Scholar

[3] G. Xu, W. Shi, M. Gong, F. Yu, J. Feng, Curing behavior and toughening performance of epoxy resins containing hyperbranched polyester, Polym. Adv. Technol. 15 (2004) 639–644.

DOI: 10.1002/pat.520

Google Scholar

[4] J.D. Liu, H. J Sue, Z.J. Thompson, F.S. Bates, M. Dettloff, G. Jacob, N. Verghese, H. Pham, Strain rate effect on toughening of nano-sized PEP-PEO block copolymer modified epoxy, Acta Mat. 57 (2009) 2691-2701.

DOI: 10.1016/j.actamat.2009.02.023

Google Scholar

[5] G. Cicala, A. Recca, C. Restuccia, Influence of hydroxyl functionalized hyperbranched polymers on the thermomechanical and morphological properties of epoxy resins, Polym. Eng. Sci. 45 (2005) 225–237.

DOI: 10.1002/pen.20242

Google Scholar

[6] D. Zhang, X. Cheng, A. Zhang, D. Jia, Toughness and reinforcement of linear unsaturated polyester resins by unsaturated hyperbranched polymer and mechanism analysis, Funct. Mat. Letters. 4 (2011) 351-355.

DOI: 10.1142/s1793604711002202

Google Scholar

[7] L. Boogh, B. Pettersson, J.A.E. Manson, Dendritic hyperbranched polymers as tougheners for epoxy resins, Polymer 40 (1999) 2249–2261.

DOI: 10.1016/s0032-3861(98)00464-9

Google Scholar

[8] F. Samperi, S. Battiato, C. Puglisi, A. Scamporrino, V. Ambrogi, L. Ascione, C. Carfagna, Combined Techniques for the Characterization of Linear–Hyperbranched Hybrid Poly(Butylene Adipate) Copolymers, J Polym Sci Part A: Polym Chem. 49 (2011).

DOI: 10.1002/pola.24800

Google Scholar

[9] P. Supaphol, N. Apiwanthanakorn, P. Krutphun, Effect of small amount of polyethylene naphthalate on isothermal crystallization spherulitic morphology polytrimethylene terephthalate, Pol. Test. 26 (2007) 985-1000.

DOI: 10.1016/j.polymertesting.2007.06.007

Google Scholar

[10] V.P. Carvalho, C.P. Ferraz, B.S. Lima Neto, Tailored norbornene-based copolymer with systematic variation of norbornadiene as a crosslinker obtained via ROMP with alternativeanime Ru catalysts, Euro. Pol. J. 48 (2012) 341-349.

DOI: 10.1016/j.eurpolymj.2011.11.011

Google Scholar

[11] T. Brocks, M.O.H. Cioffi, H.J.C. Voorwald, Effect of fiber surface on flexural strength in carbon fabric reinforced epoxy composites, Applied Surf. Sci. 274 (2013) 210-216.

DOI: 10.1016/j.apsusc.2013.03.018

Google Scholar

[12] D. Santiago, X.F. -Francos, X. Ramis, J.M. Salla, M. Sangermano, Comparative curing kinetics and thermal–mechanical properties of DGEBA thermosets cured with a hyperbranched poly(ethyleneimine) and an aliphatic triamine, Thermoch. Acta. 526 (2011).

DOI: 10.1016/j.tca.2011.08.016

Google Scholar

[13] D.M. Dhevi, S.N. Jaisankar, M. Pathak, Effect of new hyperbranched polyester of varying generations on toughening of epoxy resin through interpenetrating polymer networks using urethane linkages, Euro. Pol. J. 49 (2013) 3561-3572.

DOI: 10.1016/j.eurpolymj.2013.06.041

Google Scholar

[14] P.G. Parchuzowski, M. Kislinska, G. Rokicki, New hyperbranched polyether containing cyclic carbonate groups as a toughening agent for epoxy resin, Polymer. 48 (2007) 1857-1865.

DOI: 10.1016/j.polymer.2007.02.021

Google Scholar

[15] J.F. Fu, L.Y. Shi, S. Yuan, Q.D. Zhong, D.S. Zhang,Y. Chen, J. Wu, Morphology, toughening mechanism and thermal properties of hyperbranched epoxy modified diglycidyl ether bisphenol A interpenetranting polymer networks, Polym. Adv. Technol. 19 (2008).

DOI: 10.1002/pat.1175

Google Scholar