One-Pot Synthesis of UV-Curable Au/PEDOT Conductive Ink by Using Amphiphilic Polymer PSMH as Templates

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In this paper, we report a one-pot method to prepare a new type of UV-curable Au/PEDOT nanocomposite used in printed electronics, which use an amphiphilic polymer polystyrenesulfonate-alt-[maleic anhydride-g-(2-hydroxy-ethyl-methacrylate)] (PSMH) as a conductive ink. The synthesis included the reduction of chloroauric acid using EDOT (3, 4-Ethylenedioxythiophene).PSMH acted a dopant for PEDOT and a stabilizer of Au nanoparticles due to the ligand exchange between chloroauric acid and carboxylate group. The carbon-carbon double bonds have been introduced into this ink with UV-curable property to enhance the water resistance of this nanocomposite before inkjet-printing. The particle size of this nanocomposite is above 200 nm while the gold particles size is above 3~10 nm. This UV-curable Au/PEDOT nanocomposite can be used as a conductive ink for inkjet printing.

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101-106

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Zhou J, Lubineau G, Improving Electrical Conductivity in Polycarbonate Nanocomposites Using Highly Conductive PEDOT/PSS Coated MWCNTs, ACS Appl. Mater. Inter., 2013, 5(13): 6189-6200.

DOI: 10.1021/am4011622

Google Scholar

[2] Wang J, Lin W, Yuan L, et al., Development of a reversible fluorescent gold sensor with high selectivity, Chem. Commun., 2011, 47(46): 12506-12508.

DOI: 10.1039/c1cc15086c

Google Scholar

[3] Housni A, Zhao Y, Zhao Y, Using Polymers To Photoswitch the Aggregation State of Gold Nanoparticles in Aqueous Solution, Langmuir, 2010, 26(14): 12366-12370.

DOI: 10.1021/la101798x

Google Scholar

[4] Kesavan S, Revin S B, John S A., Fabrication, characterization and application of a grafting based gold nanoparticles electrode for the selective determination of an important neurotransmitter, J. Mater. Chem., 2012, 22(34): 17560-17567.

DOI: 10.1039/c2jm33013j

Google Scholar

[5] Kumar S S, Kumar C S, Mathiyarasu J, et al., Stabilized Gold Nanoparticles by Reduction Using 3, 4-Ethylenedioxythiophene polystyrenesulfonate in Aqueous Solutions:  Nanocomposite Formation, Stability, and Application in Catalysis, Langmuir, 2007, 23(6): 3401-3408.

DOI: 10.1021/la063150h

Google Scholar

[6] Yin H E, Lee C F, Chiu W Y., Preparation of thermally curable conductive films PEDOT: P(SS-NMA) and their performances on weather stability and water resistance, Polymer, 2011, 52(22): 5065-5074.

DOI: 10.1016/j.polymer.2011.08.044

Google Scholar

[7] Koch N, Vollmer A, Elschner A., Influence of water on the work function of conducting poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate), Appl. phys. lett., 2007, 90(4): 043512-043512-3.

DOI: 10.1063/1.2435350

Google Scholar

[8] Ying-Jie X, Min-Fang Q, Deng-Zhu G, et al., Increased work function in PEDOT: PSS film under ultraviolet irradiation, Chinese Phys. B, 2014, 23(3): 038504.

Google Scholar

[9] Kim J, You J, Kim E., Flexible Conductive Polymer Patterns from Vapor Polymerizable and Photo-Cross-Linkable EDOT Macromolecules, 2010, 43(5): 2322-2327.

DOI: 10.1021/ma9025306

Google Scholar