Effect of Calcination Temperature on Various Concentration of Zinc Substituted Calcium Phosphate Ceramics

C.M. Mardziah; Mohamad Firdaus Abdul Wahid; Koay Mei Hyie; N.R. Nik Roselina

doi:10.4028/www.scientific.net/AMM.763.30

Paper Titles

Effect of Alkaline Treatment on Tensile and Impact Strength of Kenaf/Kevlar Hybrid Composites
p.3

Influence of Radiation-Induced Defects on Magnetic Properties of Co_xNi_1-xFe₂O₄ Nanomaterials
p.9

The Compressive Properties of Kevlar/Kenaf Hybrid Composites
p.19

Tensile and Impact Strength of Coir Fibre Reinforced Polypropylene Composites: Effect of Different Temperature Conditions
p.25

Effect of Calcination Temperature on Various Concentration of Zinc Substituted Calcium Phosphate Ceramics
p.30

Effect of Single Based Binder Palm Stearin on Sintered Properties of Hydroxyapatite Scaffold
p.36

Effect of Metashaleas SCM on Mechanical and Thermal Properties in Concrete Production
p.41

Modeling and Optimizing the Hardness of the Melted Zone in Submerged Arc Welding Process Using Taguchi Method
p.47

Modeling and Optimizing of Submerged Arc Welding Process by Taguchi Design of Experiments in Presence of Magnesium Oxide Nano-Particles
p.52

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 763Effect of Calcination Temperature on Various...

Effect of Calcination Temperature on Various Concentration of Zinc Substituted Calcium Phosphate Ceramics

Abstract:

In this work, nanoscale zinc substituted calcium phosphate ceramics substituted were synthesized by simple precipitation method, performed under alkaline solution of pH 10. Three different zinc concentrations (5%, 10% and 15 mol%) were incorporated into calcium phosphate ceramics with experimental ratios of (Ca+Zn)/P were all maintained at 1.67 for easier comparison. The phase composition and lattice parameters for each sample were determined by using X-ray diffraction (XRD) method. Other characterization techniques such as Fourier transform infrared (FTIR) and field emission scanning electron (FESEM) were also utilized to investigate material’s molecule internal bonds properties and powders morphology, respectively. Based on XRD results, zinc ions addition disturbed the calcium phosphate ceramics structure causing its crystallite size to become smaller as the amount of zinc increased. After the powders undergo calcination process, the bands of PO₄ in its FTIR spectra increased while the H₂O bands decreased. FESEM results showed that the powders are uniform but irregular in shape and tend to agglomerate with increasing zinc fraction.

You might also be interested in these eBooks

Mechanical Engineering, Industrial Materials and Industrial Technologies

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 763)

Pages:

30-35

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.763.30

Citation:

Cite this paper

Online since:

May 2015

Authors:

C.M. Mardziah*, Mohamad Firdaus Abdul Wahid, Koay Mei Hyie, N.R. Nik Roselina

Keywords:

Calcination, Calcium Phosphate, Precipitation, X-Ray Diffraction, Zinc Substitution

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] J. Marchi, P. Greil, J. C. Bressiani, A. Bressiani, and F. Müller, Influence of Synthesis Conditions on the Characteristics of Biphasic Calcium Phosphate Powders, International Journal of Applied Ceramic Technology, vol. 6, pp.60-71, (2009).

DOI: 10.1111/j.1744-7402.2008.02254.x

Google Scholar

[2] D. C. Tancred, B. A. O. McCormack, and A. J. Carr, A synthetic bone implant macroscopically identical to cancellous bone, Biomaterials, vol. 19, pp.2303-2311, (1998).

DOI: 10.1016/s0142-9612(98)00141-0

Google Scholar

[3] G. S. Kumar, A. Thamizhavel, Y. Yokogawa, S. N. Kalkura, and E. K. Girija, Synthesis, characterization and in vitro studies of zinc and carbonate co-substituted nano-hydroxyapatite for biomedical applications, Materials Chemistry and Physics, vol. 134, pp.1127-1135, (2012).

DOI: 10.1016/j.matchemphys.2012.04.005

Google Scholar

[4] S. Raynaud, E. Champion, and D. Bernache-Assollant, Calcium phosphate apatites with variable Ca/P atomic ratio II. Calcination and sintering, Biomaterials, vol. 23, pp.1073-1080, (2002).

DOI: 10.1016/s0142-9612(01)00219-8

Google Scholar

[5] P. Moghimian, A. Najafi, S. Afshar, and J. Javadpour, Effect of low temperature on formation mechanism of calcium phosphate nano powder via precipitation method, Advanced Powder Technology, vol. 23, pp.744-751, (2012).

DOI: 10.1016/j.apt.2011.10.001

Google Scholar

[6] V. Simon, D. Lazăr, R. V. F. Turcu, H. Mocuta, K. Magyari, M. Prinz, M. Neumann, and S. Simon, Atomic environment in sol–gel derived nanocrystalline hydroxyapatite, Materials Science and Engineering: B, vol. 165, pp.247-251, (2009).

DOI: 10.1016/j.mseb.2009.06.010

Google Scholar

[7] J. Shepherd, D. Shepherd, and S. Best, Substituted hydroxyapatites for bone repair, Journal of Materials Science: Materials in Medicine, vol. 23, pp.2335-2347, (2012).

DOI: 10.1007/s10856-012-4598-2

Google Scholar

[8] I. R. d. Lima, G. G. Alves, G. V. d. O. Fernandes, E. P. Dias, G. d. A. Soares, and J. M. Granjeiro, Evaluation of the in vivo biocompatibility of hydroxyapatite granules incorporated with zinc ions, Materials Research, vol. 13, pp.563-568, (2010).

DOI: 10.1590/s1516-14392010000400021

Google Scholar

[9] A. Ito, M. Otsuka, H. Kawamura, M. Ikeuchi, H. Ohgushi, Y. Sogo, and N. Ichinose, Zinc-containing tricalcium phosphate and related materials for promoting bone formation, Current Applied Physics, vol. 5, pp.402-406, (2005).

DOI: 10.1016/j.cap.2004.10.006

Google Scholar

[10] M. Yamaguchi, Role of nutritional zinc in the prevention of osteoporosis, Molecular and Cellular Biochemistry, vol. 338, pp.241-254, (2010).

DOI: 10.1007/s11010-009-0358-0

Google Scholar

[11] F. Ren, R. Xin, X. Ge, and Y. Leng, Characterization and structural analysis of zinc-substituted hydroxyapatites, Acta Biomaterialia, vol. 5, pp.3141-3149, (2009).

DOI: 10.1016/j.actbio.2009.04.014

Google Scholar

[12] I. S. Gunawan, A. Naqshbandi, S. Ramesh, Synthesis of Zinc Doped-Biphasic Calcium Phosphate Nanopowder via Sol-Gel Method, Key Engineering Materials, vol. 531-532, pp.614-617, (2013).

DOI: 10.4028/www.scientific.net/kem.531-532.614

Google Scholar

[13] S. Cazalbou, C. Combes, D. Eichert, and C. Rey, Adaptative physico-chemistry of bio-related calcium phosphates, Journal of Materials Chemistry, vol. 14, pp.2148-2153, (2004).

DOI: 10.1039/b401318b

Google Scholar