Graft Copolymerization of Chitosan with L-Lactide under Microwave Irradiation

Ye Tian; Qing Hui Zeng; Ya Qing Ren; Xiao Fan He

doi:10.4028/www.scientific.net/AMM.778.120

Paper Titles

Effects of Reactive Elements (Hf and Y) on Adhesive Behaviour of Al₂O₃(0001)Fe(110) Interface: A First-Principles Study
p.100

Evolution of Cube Texture in Cu-45at.%Ni Alloy Substrates for YBCO Coated Conductors
p.105

Experimental Studies of Alternating and Direct Current Impedance Properties of Ag/AgCl Electrodes
p.110

FVM Simulation of Porthole Die Extrusion Process for a Large Caliber Aluminum Tube Profile
p.116

Graft Copolymerization of Chitosan with L-Lactide under Microwave Irradiation
p.120

Improvement of Thermal Oxidation Resistance of AISI H13 Steel via Hot-Dipped Aluminizing
p.124

Influence of Creep Model on Glass Tempering Process
p.128

Investigation on Elevated-Temperature Wear Resistance of Thermal Oxidation Coating on Ti-6Al-4V Alloy
p.132

Preparation and Properties of Graphene/TiO₂ Thin Films
p.136

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 778Graft Copolymerization of Chitosan with L-Lactide...

Graft Copolymerization of Chitosan with L-Lactide under Microwave Irradiation

Abstract:

Poly (L-lactide) was grafted onto chitosan by ring-opening copolymerization under microwave irradiation in the presence of tin octoate (Sn (Oct)₂) as catalyst. The chemical structure and physical properties of the copolymers with different feeding ratios were discussed by FTIR, DTG and X-RD, taking pure chitosan as reference. The results showed that the application of microwave irradiation in the reaction could achieve the copolymer with high grafting percentage in a short time and low temperature. The thermal stability and crystallinity were decreased with the feeding ratio increasing, attributing to the increasing of grafting percentage.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 778)

Pages:

120-123

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.778.120

Citation:

Cite this paper

Online since:

July 2015

Authors:

Ye Tian, Qing Hui Zeng*, Ya Qing Ren, Xiao Fan He

Keywords:

Chitosan, Graft Copolymerization, Microwave Irradiation, Poly (L-Lactide)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] L. NettlesD, S.H. Elder and J. A Gibert: Tissue Engineering Vol. 8(2002), p.1009.

Google Scholar

[2] A.D. Martino, M. Sittinger and M.V. Risbud: Biomaterials Vol. 26(2005), p.5983.

Google Scholar

[3] L. Zhang, Q. Ao, A.J. Wang, G.G. Lu, L.J. Kong, Y.D. Gong, N. M Zhao and X.F. Zhang: Journal of Biomedical Materials Research Part A Vol. 77A(2007), p.277.

Google Scholar

[4] F.G. Yao, W. Chen, H. Wang, H.F. Liu, K.D. Yao, P.C. Sun and H. Lin: Polymer Vol. 44(2003), p.6435.

Google Scholar

[5] S.H. Hyon, K. Jamishidi and Y. Ikada: Biomaterials Vol. 18(1997), p.1503.

Google Scholar

[6] T. Ouchi, S. Ichimura and Y. Ohya: Polymer Vol. 47(2006), p.429.

Google Scholar

[7] X. Qu, A. Wirsen and A. Albertsson: Journal of Applied Polymer Science Vol. 74(2003), p.3186.

Google Scholar

[8] Y. Wu, Y.L. Zheng, W.L. Yang, C.C. Wang, J.H. Hu and S.K. Fu: Carbohydrate Polymers Vol. 59(2005) p.165.

Google Scholar

[9] X. Qu, A. Wirsen and A.C. Albertsson: Polymer Vol. 41(2000), p.4841.

Google Scholar

[10] Y. Liu, F. Tian and K.A. Hu: Carbohydrate Research Vol. 339(2004), p.845.

Google Scholar

[11] J. Shao, Y.M. Yang and Q.Q. Zhong: Polymer Degradation and Stability Vol. 82(2003), p.395.

Google Scholar

[12] H.C. Ge, W. Pang and D.K. Luo: Carbohydrate Polymers Vol. 66(2006), p.372.

Google Scholar

[13] V. Singh, D.N. Tripathi, A. Tiwari and R. Sanghi: Journal of Applied Polymer Science Vol. 95(2005), p.820.

Google Scholar

[14] V. Singh, A. Tiwari, D.N. Tripathi and R. Sanghi: Polymer Vol. 47(2006), p.254.

Google Scholar

[15] R. Jayakumar, M. Prabaharan, R.L. Reis and J.F. Mano: Carbohydrate Polymers Vol. 62(2005), p.142.

Google Scholar

[16] T. Yui, K. Imada, K. Okuyama, Y. Obata, K. Suzuki and K. Ogawa: Macromolecules Vol. 27(1994), p.7601.

DOI: 10.1021/ma00104a014

Google Scholar

[17] H. Tsuji and H. Muramatsu: Journal of Applied Polymer Science Vol. 81(2001), p.2151.

Google Scholar