Effect of SiO2 Nanoparticles on the Mechanical and Low Velocity Impact Properties of Epoxy/Glass Composites

Article Preview

Abstract:

Flexural strength and low velocity impact properties were investigated in terms of possibile improvements due to epoxy matrix modification by SiO2 nanoparticles (1%, 2%, 3%, 5%, 7%wt.) in glass/epoxy laminates formed using hand lay-up method. The matrix resin was Hexion L285 (DGEBA) with Nanopox A410 - SiO2 (20 nm) nanoparticle suspension in the base epoxy resin (DGEBA) supplied by Evonic. Modification of epoxy matrix by variable concentrations of nanoSiO2 does not offer significant improvements in the flexural strength σg, Young’s modulus E and interlaminar shear strength for 1% 3% and 5% nanoSiO2 and for 7% a slight drop (up to ca. 15-20%) was found. Low energy (1J) impact resistance of nanocomposites represented by peak load in dynamic impact characteristics was not changed for nanocompoosites compared to the unmodified material. However at higher impact energy (3J) nanoparticles appear to slightly improve the impact energy absorption for 3% and 5%. The absence or minor improvements in the mechanical behaviour of nanocomposites is due to the failure mechanisms associated with hand layup fabrication technique: (i.e. rapid crack propagation across the extensive resin pockets and numerous pores and voids) which dominate the nanoparticle-dependent crack energy absorption mechanisms (microvoids formation and deformation).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

29-35

Citation:

Online since:

June 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.J. Kinloch, Toughening epoxy adhesives to meet today's challenges: MRS Bulletin 2003, 28(6): 445-8.

DOI: 10.1557/mrs2003.126

Google Scholar

[2] B.B. Johnsen, A.J. Kinloch, R.D. Mohammed, A.C. Taylor, S. Sprenger, Toughening mechanisms of nanoparticle-modified epoxy polymers: Polymer 48, 2007 530-5.

DOI: 10.1016/j.polymer.2006.11.038

Google Scholar

[3] Q. Zhao i S.V. Hoa, Toughening mechanisms of epoxy resins with micro/nano particles: Journal of composite materials. 2007, vol. 41, 2.

DOI: 10.1177/0021998306063361

Google Scholar

[4] A.J. Kinloch, A.C. Taylor, J.H. Lee, S. Sprenger, C. Eger, D. Egan, Toughening structural adhesives via nano-and micro-phase inclusions: Journal of Adhesion 2003, 79(8-9), 867-73.

DOI: 10.1080/00218460309551

Google Scholar

[5] Y. Xu, S.V. Hoa, Mechanical properties of carbon fiber reinforced epoxy/clay nanocomposites: Composites Science and Technology, 2008, vol. 68, 3-4.

DOI: 10.1016/j.compscitech.2007.08.013

Google Scholar

[6] W. Liu, S.V. Hoa, M. Pugh, Organoclay-modified high performance epoxy nanocomposites: Composites Science and Technology 2005, vol 65, 2.

DOI: 10.1016/j.compscitech.2004.07.012

Google Scholar

[7] Y. Huang, A.J. Kinloch, Modelling of the toughening mechanisms in rubber-modified epoxy polymers: Journal of Materials Science, 1992, vol. 27, 10.

DOI: 10.1007/bf00540702

Google Scholar

[8] J. Cho, J.Y. Chen, I.M. Daniel, Mechanical enhancement of carbon fiber/epoxy composites by graphite nanoplatelet reinforcement: Scripta materialia 56, 8 2007 685-688.

DOI: 10.1016/j.scriptamat.2006.12.038

Google Scholar

[9] Evonik Industries - Specialty Chemicals. [Online] Evonik. [cited: 20 01 2014. ] http: /corporate. evonik. com.

Google Scholar

[10] Y. Zeng, H.Y. Liu, Y.W. Mai, X.S. Du, Improving interlaminar fracture toughness of carbon fibre/epoxy laminates by incorporation of nano-particles: Composites Part B: Engineering, 2012, 43(1): 90-94.

DOI: 10.1016/j.compositesb.2011.04.036

Google Scholar

[11] M.F. Uddin, C.T. Sun, Impact resistance and toughness of composite laminates with nanoparticle – enhancedmatrix. In: Proceedings of International SAMPEL symposium and expo, Long Beach, (2008).

Google Scholar

[12] M.F. Uddin, C.T. Sun, Strength of unidirectional glass/epoxy composite with silica nanoparticle – enhanced matrix: Composites Science and Technology, 2008, vol. 68, 7-8.

DOI: 10.1016/j.compscitech.2008.02.026

Google Scholar

[13] P.N.B. Reis, J.A.M. Ferreira, Z.Y. Zhang, T. Benameur, M.O.W. Richardson, Impact strength of composites with nano-enhanced resin after fire exposure: Composites: Part B 56 (2014) 290-295.

DOI: 10.1016/j.compositesb.2013.08.048

Google Scholar

[14] S. Zhao L.S. Schadler, R. Duncan, H. Hillborg, T. Auletta., Mechanisms leading to improved mechanical performance in nanoscale alumina filled epoxy: Composites Science and Technology: 2008, vol. 68.

DOI: 10.1016/j.compscitech.2008.01.009

Google Scholar