Characterization of Peat Water Electrocoagulation Flocs from Sarawak Southern Region

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Abstract:

Sarawak located in Borneo is endowed with the vast availability of peat water sources, particularly for the state southern region. Several investigations have shown that electrocoagulation treatment with aluminium electrodes is feasible to treat peat water in which the quality is comparable to the National Water Quality Standard (NWQS). Even though electrocoagulation treatment is feasible to treat peat water, the characteristics of peat water electrocoagulation flocs have not been reported. As such, this study aims to investigate the characteristics of the electrocoagulation flocs from peat water derived from the Sarawak southern region by using batch electrocoagulation treatment. The objectives of this study are to conduct an experimental study analysis of and identify the minerals on the electrocoagulation flocs along with operating energy cost analysis of peat water batch electrocoagulation treatment. Consequently, this study has found that reaction time and current density affect the production of flocs in which the amount of flocs increases with the increasing reaction time and current density. The flocs produced are found to consist of a large fraction of oxygen (O), carbon (C), iron (Fe), and aluminium (Al) along with a small fraction of potassium (K), magnesium (Mg), calcium (Ca) and Silicon (Si). The presence of Al observed in the flocs is due to the aluminium hydroxide generated during the electrocoagulation process. The total operating cost for peat electrocoagulation with a current density of 5A and reaction time of 20 minutes is about RM0.31 per m3. As a result, the electrocoagulation of peat water process is able to treat peat water as well as produce flocs in which earth elements and heavy metals could be recovered.

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197-208

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March 2024

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[1] N. Abdul Rahman, A. Albania Linus, E.E. Jihed, U. Jata, N.K.M.F. Kumar, A. Philip, A. Yassin, A. Parabi, Experimental Studies on Continuous Electrocoagulation Treatment of Peat Water in Sarawak with Copper Electrodes, Int. J. Integr. Eng. 13 (2021) 168–176.

DOI: 10.1088/1757-899x/778/1/012126

Google Scholar

[2] N. Abdul Rahman, C. Jose Jol, A. Albania Linus, V. Ismail, Emerging Application of Electrocoagulation for Tropical Peat Water Treatment: A Review, Chem. Eng. Process. - Process Intensif. 165 (2021) 108449.

DOI: 10.1016/j.cep.2021.108449

Google Scholar

[3] N. Abdul Rahman, N.A. Tomiran, A.H. Hashim, Batch electrocoagulation treatment of peat water in Sarawak with galvanized iron electrodes, Mater. Sci. Forum. 997 MSF (2020) 127–138.

DOI: 10.4028/www.scientific.net/msf.997.127

Google Scholar

[4] I.A. Afip, K. Jusoff, Properties of a tropical sapric peat soil in sarawak, Malaysian J. Soil Sci. 23 (2019) 1–12.

Google Scholar

[5] B. Al Aji, Y. Yavuz, A.S. Koparal, Electrocoagulation of heavy metals containing model wastewater using monopolar iron electrodes, Sep. Purif. Technol. 86 (2012) 248–254.

DOI: 10.1016/j.seppur.2011.11.011

Google Scholar

[6] A.A. Al-Raad, M.M. Hanafiah, A.S. Naje, M.A. Ajeel, A.O. Basheer, T.A. Aljayashi, M.E. Toriman, Treatment of saline water using electrocoagulation with combined electrical connection of electrodes, Processes. 7 (2019).

DOI: 10.3390/pr7050242

Google Scholar

[7] F. Ali, D.L. Lestari, M.D. Putri, Peat Water Treatment as an Alternative for Raw water in Peatlands Area, IOP Conf. Ser. Mater. Sci. Eng. 1144 (2021) 012052.

DOI: 10.1088/1757-899x/1144/1/012052

Google Scholar

[8] K. Brahmi, W. Bouguerra, B. Hamrouni, E. Elaloui, M. Loungou, Z. Tlili, Investigation of electrocoagulation reactor design parameters effect on the removal of cadmium from synthetic and phosphate industrial wastewater, Arab. J. Chem. 12 (2019) 1848–1859.

DOI: 10.1080/19443994.2015.1024940

Google Scholar

[9] O.T. Can, M. Bayramoglu, The effect of process conditions on the treatment of benzoquinone solution by electrocoagulation, J. Hazard. Mater. 173 (2010) 731–736.

DOI: 10.1016/j.jhazmat.2009.08.146

Google Scholar

[10] G. Chen, X. Chen, P.L. Yue, Electrocoagulation and Electroflotation of Restaurant Wastewater, J. Environ. Eng. 126 (2000) 858–863.

DOI: 10.1061/(asce)0733-9372(2000)126:9(858)

Google Scholar

[11] Department of Environment, Environmental Quality Act report, Ministry of Science, Technology and the Environment, Putrajaya, Malaysia, 2017.

Google Scholar

[12] Department of Irrigation and Drainage, Resource Centre - Peat Swamp Development, (2017).

Google Scholar

[13] A. El-Shazly, A.A. Al-Zahrani, Y.A. Alhamed, Kinetics and Performance Analysis of Batch Electrocoagulation Unit Used for the Removal of a Mixture of Phosphate and Nitrate Ions from Industrial Effluents, J. Electrochem. Sci. 8 (2013) 3176–3185.

Google Scholar

[14] M.M. Emamjomeh, M. Sivakumar, Review of pollutants removed by electrocoagulation and electrocoagulation/flotation processes, J. Environ. Manage. 90 (2009) 1663–1679.

DOI: 10.1016/j.jenvman.2008.12.011

Google Scholar

[15] F.U. Kac, M. Kobya, E. Gengec, Removal of humic acid by fixed-bed electrocoagulation reactor: Studies on modelling, adsorption kinetics and HPSEC analyses, J. Electroanal. Chem. 804 (2017) 199–211.

DOI: 10.1016/j.jelechem.2017.10.009

Google Scholar

[16] S.U. Khan, I.H. Farooqi, M. Usman, F. Basheer, Energy efficient rapid removal of arsenic in an electrocoagulation reactor with hybrid fe/al electrodes: Process optimization using ccd and kinetic modeling, Water (Switzerland). 12 (2020) 1–13.

DOI: 10.3390/w12102876

Google Scholar

[17] K.T. Kin, H.S. Tang, S.F. Chan, S. Raghavan, S. Martinez, Treatment of chemical-mechanical planarization wastes by electrocoagulation/electro-fenton method, IEEE Trans. Semicond. Manuf. 19 (2006) 208–215.

DOI: 10.1109/tsm.2006.873511

Google Scholar

[18] V. Kuokkanen, Utilization of Electrocoagulation for Water and Wastewater Treatment and Nutrient Recovery, University of Oulu, 2016.

Google Scholar

[19] V. Kuokkanen, T. Kuokkanen, J. Ramo, U. Lassi, Electrocoagulation treatment of peat bog drainage water containing humic substances, Water Res. 79 (2015) 79–87.

DOI: 10.1016/j.watres.2015.04.029

Google Scholar

[20] M. Mamelkina, Treatment of mining waters by electrocoagulation, Lappeenranta-Lahti University of Technology LUT, 2020.

Google Scholar

[21] L. Melling, H. Ryusuke, O. Mitsuru, Sustainable agriculture development on tropical peatland, 14-21 August, Thailand., 2002.

Google Scholar

[22] H. Moayedi, M. Mosallanezhad, Physico-Chemical and Shrinkage Properties of Highly Organic Soil Treated with Non-traditional Additives, Geotech. Geol. Eng. 35 (2017) 1409–1419.

DOI: 10.1007/s10706-017-0184-1

Google Scholar

[23] M.Y.A. Mollah, P. Morkovsky, J.A.G. Gomes, M. Kesmez, J. Parga, D.L. Cocke, Fundamentals, present and future perspectives of electrocoagulation, J. Hazard. Mater. 114 (2004) 199–210.

DOI: 10.1016/j.jhazmat.2004.08.009

Google Scholar

[24] D.T. Moussa, M.H. El-Naas, M. Nasser, M.J. Al-Marri, A comprehensive review of electrocoagulation for water treatment: Potentials and challenges, J. Environ. Manage. 186 (2017) 24–41.

DOI: 10.1016/j.jenvman.2016.10.032

Google Scholar

[25] A.A. Mutalib, J.S. Lim, M.H. Wong, L. Koovai, Characterisation, Distribution and Utilization of Peat in Malaysia, Tropical Peat, in: Int. Symp. Trop. Peatl., Kuching, Sarawak, Malaysia, 1991: p.7–16.

Google Scholar

[26] B. Nvs, P.L. Saranya, Water pollutants monitoring based on Internet of Things, in: Inorg. Pollut. Water, 2020: p.371–397.

DOI: 10.1016/b978-0-12-818965-8.00018-4

Google Scholar

[27] N.A. Rahman, C. Jose Jol, A. Albania Linus, F.L. Dampam, N.S. Abdul Jalal, N. Baharudin, W.W.S. Wan Borhan, Continuous electrocoagulation treatment of Borneo tropical brackish peat water from palm oil plantation region for domestic consumption in rural coastal areas, Chem. Eng. Process. - Process Intensif. 176 (2022) 108967.

DOI: 10.1016/j.cep.2022.108967

Google Scholar

[28] Rusdianasari, Y. Bow, T. Dewi, Peat Water Treatment by Electrocoagulation using Aluminium Electrodes, IOP Conf. Ser. Earth Environ. Sci. 258 (2019).

DOI: 10.1088/1755-1315/258/1/012013

Google Scholar

[29] N.M. Sa'don, A.R. Abdul Karim, W. Jaol, W.H. Wan Lili, Sarawak Peat Characteristics and Heat Treatment, UNIMAS E-Journal Civ. Eng. Sarawak. 5 (2015) 6–12.

DOI: 10.33736/jcest.139.2014

Google Scholar

[30] E. Sakarinen, Humic acid removal by chemical coagulation, electrocoagulation and ultrafiltration, Arcada University of Applied Sciences, 2016.

Google Scholar

[31] H. Singh, B.K. Mishra, Assessment of kinetics behavior of electrocoagulation process for the removal of suspended solids and metals from synthetic water, Environ. Eng. Res. 22 (2017) 141–148.

DOI: 10.4491/eer.2016.029

Google Scholar

[32] T.C. Whitmore, A Vegetation Map of Malesia at Scale 1:5 Million, J. Biogeogr. 11 (1984) 461–471.

Google Scholar