Effect of Dye Extraction from Mangosteen Pericarp with Different Extraction Solvents for DSSC Fabrication

Article Preview

Abstract:

Dye-sensitized solar cell (DSSC) is a well-known solar cell device because it can convert electrical energy from solar energy. In addition, DSSC has many benefits to offer humankind such as low cost in production, flexibility and eco-friendliness. However, the efficiency provided for DSSC operation is still low compared to the efficiency offered by semiconductor materials. Thus, four different solvents are used to extract natural dye from mangosteen pericarp in order to increase the efficiency in DSSC: pure ethanol, ethanol containing 20 % distilled water, ethanol containing 1 % hydrochloric acid (HCl) and ethanol containing 1 % acetic acid. Other than that, the dyes are examined to observe the optical properties by using Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectroscopy (UV-Vis). FTIR analysis resulted in the functional group presence in the dyes while UV-Vis shows that absorption activity exists in the mangosteen pericarp dyes. In addition, the efficiency of mangosteen pericarp dyes with pure ethanol, ethanol containing 20 % distilled water, ethanol containing 1 % hydrochloric acid (HCl) and ethanol containing 1 % acetic acid are calculated which are 0.080 x 10-3 %, 0.554 x 10-3 %, 0.126 x 10-3 % and 0.102 x 10-3 % respectively.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

21-28

Citation:

Online since:

June 2025

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2025 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. K. Rajan and L. Cindrella, "Studies on new natural dye sensitizers from Indigofera tinctoria in dye-sensitized solar cells," Opt Mater (Amst), vol. 88, no. September 2018, p.39–47, 2019.

DOI: 10.1016/j.optmat.2018.11.016

Google Scholar

[2] R. Syafinar, N. Gomesh, M. Irwanto, M. Fareq, and Y. M. Irwan, Potential of Purple Cabbage, Coffee, Blueberry and Turmeric as Nature Based Dyes for Dye Sensitized Solar Cell (DSSC), vol. 79. Elsevier B.V., 2015.

DOI: 10.1016/j.egypro.2015.11.569

Google Scholar

[3] S. Shalini, R. Balasundara Prabhu, S. Prasanna, T. K. Mallick, and S. Senthilarasu, "Review on natural dye sensitized solar cells: Operation, materials and methods," Renewable and Sustainable Energy Reviews, vol. 51, p.1306–1325, 2015.

DOI: 10.1016/j.rser.2015.07.052

Google Scholar

[4] M. Bhogaita, A. D. Shukla, and R. P. Nalini, "Recent advances in hybrid solar cells based on natural dye extracts from Indian plant pigment as sensitizers," Solar Energy, vol. 137, p.212–224, 2016.

DOI: 10.1016/j.solener.2016.08.003

Google Scholar

[5] A. D. Zikri and J. Gunlazuardi, "Preparation of a TiO2-based dye-sensitized solar cell comprising anthocyanin from mangosteen pericarp (Garcinia mangostana, L.) as the sensitizer: Co-pigmentation effect on sensitizer and solar cell efficiency," J Phys Conf Ser, vol. 1442, no. 1, 2020.

DOI: 10.1088/1742-6596/1442/1/012062

Google Scholar

[6] A. Bist and S. Chatterjee, "Review on Efficiency Enhancement Using Natural Extract Mediated Dye-Sensitized Solar Cell for Sustainable Photovoltaics," Aug. 01, 2021, John Wiley and Sons Inc.

DOI: 10.1002/ente.202001058

Google Scholar

[7] R. Nur Iman, M. Younas, K. Harrabi, and A. Mekki, "A comprehensive review on advancements and optimization strategies in dye-sensitized solar cells: Components, characterization, stability and efficiency enhancement," Inorg Chem Commun, vol. 165, no. April, p.112488, 2024.

DOI: 10.1016/j.inoche.2024.112488

Google Scholar

[8] G. Calogero, J. H. Yum, A. Sinopoli, G. Di Marco, M. Grätzel, and M. K. Nazeeruddin, "Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells," Solar Energy, vol. 86, no. 5, p.1563–1575, 2012.

DOI: 10.1016/j.solener.2012.02.018

Google Scholar

[9] N. A. M. Arifin, H. Salleh, A. N. Dagang, N. A. N. Ali, N. S. Alias, and N. H. Kamarulzaman, "Photodegradation effect on optical properties of mangosteen pericarp, black grape peel and violet bougainvillea flowers as photosensitizer for solar cell application," J Teknol, vol. 83, no. 5, p.109–117, 2021.

DOI: 10.11113/jurnalteknologi.v83.16729

Google Scholar

[10] K. Sharma, V. Sharma, and S. S. Sharma, "Dye-Sensitized Solar Cells: Fundamentals and Current Status," Nanoscale Res Lett, vol. 13, 2018.

DOI: 10.1186/s11671-018-2760-6

Google Scholar

[11] J. M. R. C. Fernando and G. K. R. Senadeera, "Natural anthocyanins as photosensitizers for dye-sensitized solar devices," Curr Sci, vol. 95, no. 5, p.663–666, 2008, [Online]. Available: https://www.jstor.org/stable/24102808

Google Scholar

[12] N. Sofyan, A. Ridhova, A. H. Yuwono, and A. Udhiarto, "Fabrication of solar cells with TiO2 nanoparticles sensitized using natural dye extracted from mangosteen pericarps," International Journal of Technology, vol. 8, no. 7, p.1229–1238, 2017.

DOI: 10.14716/ijtech.v8i7.692

Google Scholar