Synthesis and Fluorescence Properties of a New Eu(III) Complexes with β-Diketone Ligand

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Abstract:

A novel β-diketone 4-[4-(Dibenzylamino) phenyl]-2,4-dioxobutanoic (DPD) and its corresponding Eu3+ complex with 1,10-phenanthroline were synthesized. The structure, thermal behaviour and fluorescence property of the complex was characterized by Fourier Transform Infrared (FT-IR), thermal gravimetric analysis (TGA) and fluorescence spectrophotometer. The fluorescence characterization shown that the addition of β-diketone and 1,10-phenanthroline enhance the fluorescence intensity of the complex. Eu3+ complex was considered to be a valuable organic light-emitting material with bright red fluorescence because of its strong emission band. Furthermore, the thermal stability characterizarion shows that the obtained rare earth β-diketone complexes have good thermostability.

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11-14

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July 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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