Research on Photochromic Materials with Synthesis and Properties of 1-(3,5-Dimethyl-4-isoxazolyl)-2-[2-methyl-5-(p-ethoxyphenyl)-3-thienyl]perfluorocyclopentene

Guan Ming Liao; Dan Dan Xue; Chun Hong Zheng; Shou Zhi Pu

doi:10.4028/www.scientific.net/AMR.1003.27

Paper Titles

Synthesis and Fluorescence Properties of a New Eu(III) Complexes with β-Diketone Ligand
p.11

Synthesis and Photochromism Studies of 1-(3,5-dimethyl-4-isoxazole)-2-[2-methyl-5-naphthyl-3-thienyl] perfluorocyclopentene
p.15

Research on Photochromic Materials with Synthesis and Properties of a New Unsymmetrical Diarylethene 1-(2-cyano-1,5-dimethyl-4-pyrryl)-2-{2-methyl-[5-(4-methylene-bromine)phenyl]-3-thienyl} Perfluorocyclopentene
p.19

Research on Photochromic Compounds with Synthesis and Properties of a Novel Unsymmetrical Diarylethene with a Benzothiophene and a Pyrrole Group
p.23

Research on Photochromic Materials with Synthesis and Properties of 1-(3,5-Dimethyl-4-isoxazolyl)-2-[2-methyl-5-(p-ethoxyphenyl)-3-thienyl]perfluorocyclopentene
p.27

Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(9-phenanthrene)-3-thienyl] perfluorocyclopentene
p.31

Research on Photochromic Materials with Synthesis and Application of 1-(2-methyl-3-benzothienyl)-2-[2-methyl-(5-ethynyl)trimethylsilane-3-thienyl] Perfluorocyclopentene
p.35

Research on Photochromic Compounds with Efficient Synthesis and Photochromic Properties of 1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(4-pentylphenyl)-3-thienyl] perfluorocyclopentene
p.39

Research on Photochromic Compounds with Efficient Synthesis and Photochromic Properties of 1-(2-methyl-5-chlorine-3-thienyl)-2-[2-methyl -5-(4-chlorophenyl)-3-thienyl] Perfluorocyclopentene
p.43

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Research on Photochromic Materials with Synthesis and Properties of 1-(3,5-Dimethyl-4-isoxazolyl)-2-[2-methyl-5-(p-ethoxyphenyl)-3-thienyl]perfluorocyclopentene

Abstract:

An asymmetrical photochromic diarylethene 1-(3,5-Dimethyl-4-isoxazolyl)-2-[2-methyl-5-(p-ethoxyphenyl)-3-thienyl] perfluorocyclopentene (1o) was synthesized and its photochromic properties were investigated. Upon irradiation with 297 nm UV light, 1o exhibited photochromism in hexane solution. The kinetic experiments showed that the cyclization and cycloreversion processes were zeroth and first order reaction, respectively. Moreover, diarylethene 1o also exhibited obviously fluorescence switches along with the photochromism.

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Periodical:

Advanced Materials Research (Volume 1003)

Pages:

27-30

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1003.27

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Online since:

July 2014

Authors:

Guan Ming Liao, Dan Dan Xue, Chun Hong Zheng*, Shou Zhi Pu

Keywords:

Diarylethene, Fluorescence, Isoxazole Moiety, Kinetic, Photochromism

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References

[1] M. Irie: Chem. Rev. Vol. 100 (2000), p.1685.

Google Scholar

[2] H.H. Liu and Y. Chen: Dyes Pigm. Vol. 89 (2011), p.212.

Google Scholar

[3] M. Morimoto, S. Kobatake and M. Irie: J. Am. Chem. Soc. Vol. 125 (2003), p.11080.

Google Scholar

[4] M. Irie, O. Miyatake, K. Uchida and T. Eriguchi: J. Am. Chem. Soc. Vol. 116 (1994), p.9894.

Google Scholar

[5] S.Z. Pu, C.H. Zheng, Z.G. Le, G. Liu and C.B. Fan: Tetrahedron. Vol. 64 (2008), p.2576.

Google Scholar

[6] S.Z. Pu, H. Li, G. Liu, W.J. Liu, S.Q. Cui and C.B. Fan: Tetrahedron. Vol. 67 (2011), p.1447.

Google Scholar

[7] G. Liu, M. Liu, S.Z. Pu, C.B. Fan and S.Q. Cui: Tetrahedron. Vol. 68 (2012), p.2267.

Google Scholar

[8] S.Z. Pu, Z.P. Tong, G. Liu and R.J. Wang. J: Mater. Chem. C. Vol. 1 (2013), p.4726.

Google Scholar

[9] S.Z. Pu, G. Liu and J.K. Xu: Org. Lett. Vol. 9 (2007), p.2139.

Google Scholar

[10] T. Fukaminato, T. Kawai, S. Kobatake and M. Irie: J. Phys. Chem. B. Vol. 107 (2003), p.8372.

Google Scholar

[11] H. Tian, B.Z. Chen, H.Y. Tu and K. Müllen: Adv. Mater. Vol. 14 (2002), p.918.

Google Scholar

[12] S.Z. Xiao, T. Yi, Y.F. Zhou, Q. Zhao, F.Y. Li and C.H. Huang: Tetrahedron. Vol. 62 (2006), p.10072.

Google Scholar