Effect of Applied Voltage on the Formation of Self-Organized Iron Oxide Nanoporous Film in Organic Electrolyte via Anodic Oxidation Process and their Photocurrent Performance

Article Preview

Abstract:

Anodisation of iron foil was done to produce anodic film with nanoporous structure. The effect of anodic voltage on the morphology of the anodic oxide formed was investigated. Anodic film formed on iron foil anodised at 10 V is rather compact no obvious pores. Pores can be detected on oxide anodised at 30 V despite not very uniform. For foil anodised at 50 V, 1.8 µm thick anodic layer which consisted of uniform circular pores is observed. This film was then annealed at 450°C for 3 h in air as to induce crystallinity. The annealed nanoporous film exhibits a light illuminated photocurrent of 0.45 mA in 1 M NaOH + H2O2 solution.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

99-103

Citation:

Online since:

August 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P. Xu, et al., Use of iron oxide nanomaterials in wastewater treatment: A review. Science of The Total Environment. 2012. 424(0): pp.1-10.

Google Scholar

[2] H.E. Prakasam, et al., Synthesis and photoelectrochemical properties of nanoporous iron (III) oxide by potentiostatic anodization. Nanotechnology. 2006. 17: pp.4285-4291.

DOI: 10.1088/0957-4484/17/17/001

Google Scholar

[3] A. Jagminas, et al., Compositional and structural characterization of nanoporous produced by iron anodizing in ethylene glycol. Applied Surface Science. 2011. 257: pp.3893-3897.

DOI: 10.1016/j.apsusc.2010.11.113

Google Scholar

[4] H. Cheng, et al., Electrochemical fabrication and optical properties of periodically structured porous Fe2O3 films. Electrochemistry Communications. 2012. 20: pp.178-181.

DOI: 10.1016/j.elecom.2012.05.007

Google Scholar

[5] S.P. Albu, A. Ghicov, and P. Schmuki, High aspect ratio, self-ordered iron oxide nanopores formed by anodization of Fe in ethylene glycol/NH4F electrolytes. Phys. Status Solidi RRL. 2009. 3(2-3): pp.64-66.

DOI: 10.1002/pssr.200802285

Google Scholar