Three-Dimensional Periodic Hematite Photocatalysts Fabricating by Direct Writing Method

Article Preview

Abstract:

Three-dimensional (3-D) periodic hematite scaffold was successfully fabricated by direct writing method as a catalyst for degradation of organic contaminants. Photo-catalytically active α-Fe2O3 nanoparticles have been synthesized by sol-gel technique. Aqueous slurries of iron oxides were freeform fabricated to produce hematite scaffolds with a 3-D periodic architecture and multiscale porosity. The catalytic activity of the hematite scaffolds was evaluated in the degradation of Methylene Blue (MB). It was found that the degradation rate of MB dye was over 83%. The result strongly indicates that the hematite scaffolds exhibits a high catalytic activity. Moreover, this work provides an important step forward in the creation of suitable structures for photocatalyst.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1025-1026)

Pages:

621-627

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Chen, L.N. Xu, W.Y. Li and X.L. Gou: Adv. Mater., Vol. 17 (2005), p.582.

Google Scholar

[2] M.A. Gondal, A. Hameed, Z.H. Yamani and A. Suwaiyan: Chem. Phys. Lett., Vol. 385 (2004), p.111.

Google Scholar

[3] T. Ohmori, H. Takahashi, H. Mametsuka and E. Suzuki: Phys. Chem. Chem. Phys., Vol. 2 (2000), p.3519.

Google Scholar

[4] H.J. Zhou and S.S. Wong: ACS Nano, Vol. 2 (2008), p.944.

Google Scholar

[5] S.K. Maji, N. Mukherjee, A. Mondal and B. Adhikary: Polyhedron, Vol. 33 (2012), p.145.

Google Scholar

[6] G.K. Zhang, Y.Y. Gao, Y.L. Zhang and Y. Guo: Environ. Sci. Technol., Vol. 44 (2010), p.6384.

Google Scholar

[7] J. Bandara, J.A. Mielczarski, A. Lopez and J. Kiwi: Appl. Catal. B: Environ., Vol. 34 (2001), p.321.

Google Scholar

[8] F. Herrera, A. Lopez, G. Mascolo, P. Albers and J. Kiwi: ApplCatal B: Environ., Vol. 29 (2001), p.147.

Google Scholar

[9] T. Tsoncheva, M. Dimitrov, D. Paneva, I. Mitov, R. Köhn, M. Fröba and C. Minchev: Catal. lett. Vol. 74 (2001), p.285.

DOI: 10.1023/a:1017918001654

Google Scholar

[10] T. Kawahara, K. Yamada and H. Tada: J Colloid Interface Sci., Vol. 294 (2006), p.504.

Google Scholar

[11] J. Fernandez, J. Bandara, A. Lopez, P. Buffat and J. Kiwi: Langmuir, Vol. 15 (1999), p.185.

Google Scholar

[12] J.Y. Feng, X.J. Hu and P.L. Yue: Environ. Sci. Technol., Vol. 38 (2004), p.269.

Google Scholar

[13] J.E. Smay, G.M. Gratson, R.F. Shepherd, J. CesaranoIII and J.A. Lewis: Adv. Mater., Vol. 14 (2002), p.1279.

Google Scholar

[14] R.B. Rao, K.L. Krafcik, A. M Morales and J.A. Lewis: Adv. Mater., Vol. 17 (2005), p.289.

Google Scholar

[15] Q. Li and J.A. Lewis: Adv. Mater., Vol. 15 (2003), p.1639.

Google Scholar

[16] J.A. Lewis, J.E. Smay, J. Stuecker and J. CesaranoIII: J. Am. Ceram. Soc., Vol. 89 (2006), p.3599.

Google Scholar

[17] M.P. Rao, A.J. Sanchez-Herencia, G.E. Beltz, R.M. McMeeking, F.F. Lange: Science, Vol. 286 (1999), p.102.

Google Scholar

[18] R. Soundararajan, G. Kuhn, R. Atisivan, S. Bose, A. Bandyopadhyay: J. Am. Ceram. Soc., Vol. 84 (2001), p.509.

Google Scholar

[19] A. Bandyopadhyay: Adv. Eng. Mater., Vol. 1 (1999), p.199.

Google Scholar

[20] M. Allahverdi, S.C. Danforth, M. Jafari and A. Safari: J. Eur. Ceram. Soc., Vol. 21 (2001), p.1485.

Google Scholar

[21] A. Bandyopadhyay , R.K. Panda, V.F. Janas, M.K. Agarwala, S.C. Danforth and A. Safari: J. Am. Ceram. Soc., Vol. 80 (1997), p.1366.

Google Scholar

[22] B.D. Gates: Science, Vol. 323 (2009), p.1566.

Google Scholar

[23] J.E. Smay, J. CesaranoⅢ, B.A. Tuttle and J.A. Lewis: J. Appl. Phys., Vol. 92 (2002), p.6119.

Google Scholar

[24] L.G. Griffith and G. Naughton: Science, Vol. 295 (2002), p.1009.

Google Scholar

[25] S. Michna, W. Wu and J.A. Lewis: Biomaterials Vol. 26 (2005), p.5632.

Google Scholar

[26] W. Wu, C.J. Hansen, A.M. AragÓn, P.H. Geubelle, S.R. White and J.A. Lewis: Soft Matter., Vol. 6 (2010), p.739.

Google Scholar

[27] R.A. Barry III, R.F. Shepherd, J.N. Hanson, R.G. Nuzzo, P. Wiltzius and J.A. Lewis: Adv. Mater., Vol. 21 (2009), p.2407.

Google Scholar

[28] J.D. Joannopoulos, P.R. Villeneuve and S. Fan: Nature, Vol. 386 (1997), p.143.

Google Scholar

[29] Y.A. Vlasov, X.Z. Bo, J.C. Sturm and D.J. Norris: Nature, Vol. 414 (2001), p.289.

Google Scholar

[30] A. VanBlaaderen, R. Ruel and P. Wiltzius: Nature, Vol. 385 (1997), p.321.

Google Scholar