Synthesis, Characterization and Photophysical Properties of a New CuI Complexe Contain Bis[2-(diphenylphosphino)phenyl]ether and 2-(anthracen-9-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline

Ji Ling He

doi:10.4028/www.scientific.net/AMR.1033-1034.1163

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Synthesis, Characterization and Photophysical Properties of a New Cu^I Complexe Contain Bis[2-(diphenylphosphino)phenyl]ether and 2-(anthracen-9-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1033-1034Synthesis, Characterization and Photophysical...

Synthesis, Characterization and Photophysical Properties of a New Cu^I Complexe Contain Bis[2-(diphenylphosphino)phenyl]ether and 2-(anthracen-9-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline

Abstract:

In this paper, a new diimine ligand of 2-(anthracen-9-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline(D1) and its corresponding Cu^I complex contain Bis[2-(diphenylphosphino)phenyl]ether were synthesized and characterized by ¹H NMR successfully. Experimental data confirm that Complex [Cu(D1)(DPEphos)](PF₆) is high-energy-emitting one. The broad band emission upon excitation at λ = 400 nm with the emission maximum locates at λ = 579 nm was observed. This makes them potential candidates as cheap emitting materials.

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Advanced Materials Research (Volumes 1033-1034)

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1163-1166

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https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.1163

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October 2014

Authors:

Ji Ling He

Keywords:

1,10-Phenanthroline, Copper(I) Complex, Photoluminescence (PL)

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