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Synthesis and Photophysical Properties of Iridium(III) Complex with Cyclometalated Styrylbenzothiazole Ligand

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Abstract:

New red phosphorescent material, (E)-2-(4-fluorostyryl) benzo [d] thiazole (4-FSBT) iridium (III) dibenzoylmethane (DBM) complex [(4-FSBT)2Ir (DBM)] is synthesized from 2-methyl benzothiazole, 4-fluorobenzaldehyde, iridium trichloride anhydrate and DBM. The complex is characterized by MS and 1H-NMR. (4-FSBT)2Ir (DBM) gives a photoluminescence at 625.8nm, phosphorescent quantum yield: Φ(4-FSBT)2Ir (DBM) = 0.2 and EHOMO = -4.7 eV, ELUMO = -2.5eV, respectively. The complex may be a promising electrophosphorescent material.

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Periodical:

Advanced Materials Research (Volumes 1033-1034)

Pages:

342-345

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.342

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Online since:

October 2014

Authors:

Guo Yong Xiao, Ying Wang, Hai Jun Chi, Yun Hua Lu, Ying Qian Xu, Jun Yi Hu*, Zhi Zhi Hu, Qiu Bai Sun

Keywords:

Iridium Complex, Phosphorescent Material, Styrylbenzothiazole

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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