Liquid-Phase Oxidative Degradation of the Damaged or Expired Medicinal Products

Tatyana Volgina; Viktor T. Novikov; Oksana Yu. Fedorova

doi:10.4028/www.scientific.net/AMR.1040.327

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1040Liquid-Phase Oxidative Degradation of the Damaged...

Liquid-Phase Oxidative Degradation of the Damaged or Expired Medicinal Products

Abstract:

A method of oxidative mineralization of the salicylic acid and its derivatives as well as medicinal products containing salicylic acid as the active ingredient was investigated. Destruction of the organic compounds is possible both in the electrolyte under the oxidant, electrochemically formed in situ in the sulphuric acid solutions, and at the anode so. Simultaneously, at the cathode, reduction of the zinc ions, contained in a number of medicinal products, is possible. Final products of the oxidation are simple non-toxic organic compounds, carbon dioxide, and water. This process is the most effective in the 40% sulphuric acid at the current density of 0.5–0.8 A/cm² and the temperature of 30–50 °C.

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Periodical:

Advanced Materials Research (Volume 1040)

Pages:

327-330

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1040.327

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Online since:

September 2014

Authors:

Tatyana Volgina*, Viktor T. Novikov, Oksana Yu. Fedorova

Keywords:

Electrochemical Oxidation, Electrolysis of Sulphuric Acid, Indirect Oxidation, Lead Electrode, Reduction, Salicylic Acid (SA), Waste Disposal

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References

[1] Guang-Guo Ying, Rai S. Kookanab and Dana W. Kolpin. Occurrence and removal of pharmaceutically active compounds in sewage treatment plants with different technologies, J. Environ. Monit., 11 (2009) 1498–1505.

DOI: 10.1039/b904548a

Google Scholar

[2] B. A. Adomovich, A.B. Derbichev, V.I. Dudov. Novaya tehnologiya unichtozheniya medicinckih othodov. Ekologiya I promishlennost Rossii, 3 (2005), 10–14.

Google Scholar

[3] B. E. Paton, A. V. Chernec, G. S. Marinskii, V. N. Korzhikov, V. S. Petrov. Perspektivy primeneniya plazmennyh tehnologii dlya unichtozheniya i pererabotki medizinckih i drugih opasnyh othodov. Sovremennaya elektrometallurgiya, 3 (2005), p.54.

Google Scholar

[4] Bernardo A. Frontana-Uribe, R. Daniel Little, Jorge G. Ibanez, Agustґın Palma and Ruben Vasquez-Medrano. Organic electrosynthesis: a promising green methodology in organic chemistry. Green Chem., 2010, 12, 2099–2119.

DOI: 10.1039/c0gc00382d

Google Scholar

[5] T. N. Volgina, V. T. Novikov, Indirect Electrochemical Liquid-Phase Oxidation of Salicylic and Sulfosaticylic Acide, Russian journal of applied chemistry, 6 (2008), 1081–1083.

DOI: 10.1134/s1070427208060335

Google Scholar

[6] M. D. Vedenyapina, A. K. Rakishev, A. A. Vedenyapin, A. M. Skundin, T. L. Kulova, E. D. Strelcova. Mehanizm elektrokataliticheskogo okisleniya salicilovoi kisloty v kislyh rastvorah. Kondensirovannye sredy I mezhfaznye granici, 1 (2007), 26–31.

Google Scholar