p-Nitrotoluene Bromination Using Barium Fluorobromate Ba(BrF4)2

Article Preview

Abstract:

It was shown that Ba (BrF4)2 acts like a highly-active brominating agent in case of interaction with p-nitrotoluene, the pure 3-bromo-nitrotoluene is formed. It was shown, that typical electrophilic bromination of aromatic compound with electron-donating and electron-accepting substituents occurs without any catalysts and hard conditions.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

337-341

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Rosen S., Bromination of Deactivated Aromatics Using BrF3 without a Catalyst, J. Org. Chem. 58 (1993) 239-240.

DOI: 10.1021/jo00053a043

Google Scholar

[2] Sobolev V.I., Radchenko V.B., Ostvald R.V., Filimonov V.D., Zherin I.I., Bulletin of the Tomsk Polytechnic University 322 No. 3 (2013) 44-49.

Google Scholar

[3] Sobolev V. I. , Zherin I. I. , Ostvald R. V. , Ivlev S. I. , Filimonov V. D. , Postnikov P. S., Halon 1301 Synthesis by Using Fluoroxidants, 7th International Forum on Strategic Technology, IFOST 2012; Tomsk; Russian Federation; 18 September 2012 through 21 September 2012. 1 (2012).

DOI: 10.1109/ifost.2012.6357502

Google Scholar

[4] Ivlev S. I., Woidy P., Sobolev V. I., Zherin I. I., Ostvald R. V , Kraus F., On Tetrafluorobromates(III): Crystal Structures of the Dibromate CsBr2F7 and the Monobromate CsBrF4, Zeitschrift fur anorganische und allgemeine Chemie. 639 (2013).

DOI: 10.1002/zaac.201300290

Google Scholar

[5] STOE WinXPOW, Stoe & Cie GmbH, Darmstadt, (2011).

Google Scholar

[6] V. Petricek, M. Dusek, L. Palatinus, Jana 2006, The Crystallographic Computing System, Praha, Czech Republic, (2006).

Google Scholar

[7] Sharpe A. G., Emeleus Н. J. Chemistry of the Inter-halogen Compounds. Part I. The Reaction of Bromine Trifluoride with Metallic Halides., J. Chem. Soc. (1948) 2135.

DOI: 10.1039/jr9480002135

Google Scholar

[8] Rosen S., General Method for the Preparation of b, b-Difluoroacrylates Using BrF3, Journal of Organic Chemistry. 69 (2004) 8786–8788.

Google Scholar

[9] Suhoverhov V.F., Chemistry of Flourohalogenates, Nauka, Moscow, (1968).

Google Scholar

[10] Rozen S., Attaching the Fluorine Atom to Organic Molecules Using BrF3 and Other Reagents Directly Derived from F2, Accounts of Chemical Research. 8 (2005) 803–812.

DOI: 10.1002/chin.200607263

Google Scholar

[11] Rozen S., Selective Reactions of Bromine Trifluoride in Organic Chemistry, Advanced Synthesis & Catalysis. 352 (2010) 2691–2707.

DOI: 10.1002/adsc.201000482

Google Scholar

[12] Information on http: /sdbs. db. aist. go. jp.

Google Scholar