Sol-Gel Synthesis of Chelate Containing Materials for Gas Chromatography

Mikhail A. Gavrilenko; Yurii G. Slizhov; Zhanna V. Faustova; Tatiana A. Kasymova; Nataliya A. Gavrilenko

doi:10.4028/www.scientific.net/AMR.1040.448

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1040Sol-Gel Synthesis of Chelate Containing Materials...

Sol-Gel Synthesis of Chelate Containing Materials for Gas Chromatography

Abstract:

The adsorption properties of mesoporous chelate containing sorbents which were prepared in two phases with europium and copper acetylacetonate complexes and PEG-115 as surfactant, were evaluated by column experiments.The adsorption properties of mesoporous silica with chelate complexes for some organic compounds were evaluated by gas chromatography. The best separation was achieved for europium acetylacetonate. From specific retention volumes measured at various temperatures the thermodynamic parameters of separation is discussed. Mutual separation of oxygen containing substances could also be demonstrated.

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Periodical:

Advanced Materials Research (Volume 1040)

Pages:

448-452

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1040.448

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Online since:

September 2014

Authors:

Mikhail A. Gavrilenko*, Yurii G. Slizhov, Zhanna V. Faustova, Tatiana A. Kasymova, Nataliya A. Gavrilenko

Keywords:

Chelate, Gas Chromatography, Sorbent, Synthesis

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References

[1] A. Fidalgo, L. Mihargo, Correlation between physical properties and structure of silica xerogels, Journal of Non-Crystalline Solids, 347 (2004) 128-137.

DOI: 10.1016/j.jnoncrysol.2004.07.059

Google Scholar

[2] Zh. Huijuan, W. Jun, Zh. Longping, Facile Synthesis of Monodisperse Microspheres and Gigantic Hollow Shells of Mesoporous Silica in Mixed Water-Ethanol Solvents, Langmuir, 23 (2007) 1107-1113.

DOI: 10.1021/la062542l

Google Scholar

[3] K.Y. Ho, G. Mckay, K.L. Yeung, Selective Adsorbents from Ordered Mesoporous Silica, Langmuir, 19 (2003) 3019-3024.

DOI: 10.1021/la0267084

Google Scholar

[4] B.L. Newalkar, N.V. Choudary, P. Kumar, S. Komarneni, T.S.G. Bhat, Exploring the Potential of Mesoporous Silica, SBA-15, as an Adsorbent for Light Hydrocarbon Separation, Chemical Materials, 14 (2002) 304-309.

DOI: 10.1021/cm0106466

Google Scholar

[5] O.G. Ellert, V.M. Novotortsev, M.V. Tsodikov, Certain aspects of the formation and identification of nanosized oxide components in heterogeneous catalysts prepared by different methods, Russian chemical reviews, 8 (2010) 693-712.

DOI: 10.1070/rc2010v079n08abeh004108

Google Scholar

[6] Yu.G. Slizhov, M.A. Gavrilenko, Complexation with Metal Chelates at the Phase Interface in Gas Chromatography, Russian Journal of Coordination Chemistry, 10 (2002) 736-752.

DOI: 10.1023/a:1020407629841

Google Scholar

[7] Zh.V. Faustova, Yu.G. Slizhov, M.A. Gavrilenko, Chromatographic properties of mesoporous silica gel modified with acetylacetonates of europium and copper, Russian Journal of Physical Chemistry, 7 (2013) 1215 – 1217.

DOI: 10.1134/s0036024413060083

Google Scholar

[8] A. Vinu, V. Murugesan, M. Hartmann, Adsorption of Lysozyme over Mesoporous Molecular Sieves MCM-41 and SBA-15: Influence of pH and Aluminum Incorporation. Journal of Physical Chemistry B, 108 (2004) 7323-7330.

DOI: 10.1021/jp037303a

Google Scholar

[9] A. Matsumoto, H. Misran, K. Tsutsumi, Adsorption Characteristics of Organosilica Based Mesoporous Materials, Langmuir, 20 (2004) 7139-7145.

DOI: 10.1021/la0360409

Google Scholar

[10] Y. Miyake, T. Kato, The Formation Process of Spherical Mesoporous Silica with Reverse Nanostructure of MCM41 in a Two-Phase System, Journal of Chemical Engeneering of Japan, 38 (2005) 60-66.

DOI: 10.1252/jcej.38.60

Google Scholar