The Effect of Reaction Parameters on the Structural NaYF4 Microcrystals

Xin Li Li; Zhan Hong Ma; Yun Fei Wang; Feng Zhang Ren; Rong Hui Xu

doi:10.4028/www.scientific.net/AMR.1044-1045.141

Paper Titles

Synthesis of Zeolite from Blast Furnace Slag Using Alkali Fusion with Addition of EDTA
p.124

The Compatibility Research of the Organic Montmorillonites with SEBS
p.128

The Compositional Effect of Water-Soluble POSS Hybrid PNIPA Nanocomposite Hydrogels
p.133

The Effect of Polymerization Mode on the POSS Hybrid PVA Hydrogels
p.137

The Effect of Reaction Parameters on the Structural NaYF₄ Microcrystals
p.141

The Effect of Water-Soluble POSS on the Swelling Behavior of Hybrid PDMAEMA Nanocomposite Hydrogels
p.145

The Mechanical Properties and Microstructure of High Temperature Ti Alloys with Minor Addition
p.149

The Study of Impact Behaviour of Two Types of Glass Fibre Reinforced Polymer (GFRP) Subjected to Low Velocity Impact
p.153

Thermally Activated Delayed Fluorescence Materials Based on Carbazole/Sulfone
p.158

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1044-1045The Effect of Reaction Parameters on the...

The Effect of Reaction Parameters on the Structural NaYF₄ Microcrystals

Abstract:

NaYF4 microcrystals were synthesized using a hydrothermal method, and the effects of the EDTA and NaF addition amount on the crystal structure, morphology and size were systematically studied. When the NaF addition amount increase, the size of the NaYF4 microcrystal increase, the excess F- ions promote the formation of β-phase of NaYF4. EDTA significantly modifies the morphology of the crystals. When addition the EDTA the crystals transition from irregular silkworm-like microcrystal to hexagonal microprisms. And the EDTA also promote the hexagonal phase formation.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 1044-1045)

Pages:

141-144

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1044-1045.141

Citation:

Cite this paper

Online since:

October 2014

Authors:

Xin Li Li*, Zhan Hong Ma, Yun Fei Wang, Feng Zhang Ren, Rong Hui Xu

Keywords:

Crystal Structure, Hexagonal Phase NaYF₄, Morphology

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] M.H. Huang, S. Mao, H. Feick, et al. Room-temperature ultraviolet nanowire nanolasers, Science. 292(2001)1897-1899.

DOI: 10.1126/science.1060367

Google Scholar

[2] G. Rumbles. Solid-state optics: A laser that turns down the heat, Nature, 409(2001)572-573.

DOI: 10.1038/35054649

Google Scholar

[3] M.Y. Ding, W. J. Huang, L. H. Cao, et al, Flux growth of honeycomb-like β-NaYF4: Yb3+, Er3+/Tm3+ crystals with multicolor up-conversion luminescence, Materials Letters 86 (2012) 58-61.

DOI: 10.1016/j.matlet.2012.07.031

Google Scholar

[4] Y. C. Jiao, X.Y. Gao, J.X. Lu, et al, Hydrothermal synthesis of the intense green photoluminescence of hexagonal phaseNaYF4: Yb3+/Er3+ microcrystals, Journal of Alloys and Compounds, 549 (2013) 245-253.

DOI: 10.1016/j.jallcom.2012.09.056

Google Scholar

[5] L.Y. Wang, Y.D. Li, Controlled synthesis and luminescence of lanthanide doped NaYF4 nanocrystals, Chem. Mater. 19 (2007) 727-734.

DOI: 10.1021/cm061887m

Google Scholar

[6] P. Ghosh, A. Patra, tuning of crystal phase and luminescence properties of Eu3+ doped sodium yttrium fluoride nanocrystals, J. Phys. Chem. C 112 (2008) 3223-3231.

DOI: 10.1021/jp7099114

Google Scholar