A Novel Approach on Proton Exchange Membrane Free Direct Formic Acid Self-Electrolyte Fuel Cell

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Abstract:

A novel approach was performed to eliminate the expensive proton exchange membrane (PEM) from the direct formic acid fuel cell (DFAFC). In the new designed PEM-free direct formic acid self-electrolyte fuel cell (SEFC), formic acid performed the functions of both fuel and ion conductor because of it can be ionized in the aqueous solution. Porous PTFE film was used as the separator in the SEFC to isolate the electron transport inside the fuel cell. This acidic SEFC utilizing Pt as anodic/cathodic catalysts can achieve a power density greater than 1.0 mW cm–2, which was about 1/5 of that of a traditionally PEM-equipped DFAFC with the same catalysts, after the optimization of thickness and porosity of the porous PTFE film.

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Advanced Materials Research (Volumes 1049-1050)

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806-808

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Wang CY. Fundamental models for fuel cell engineering. Chem Rev 2004; 104: 4727-65.

Google Scholar

[2] Wang Y, Chen KS, Mishler J, Cho SC, Adroher XC. A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research. Appl Energy 2011; 88: 981-1007.

DOI: 10.1016/j.apenergy.2010.09.030

Google Scholar

[3] Kreuer KD, Paddison SJ, Spohr E, Schuster M. Transport in proton conductors for fuel-cell applications: Simulations, elementary reactions, and phenomenology. Chem Rev 2004; 104: 4637-78.

DOI: 10.1021/cr020715f

Google Scholar

[4] Xuan J, Leung MKH, Leung DYC, Wang HZ. Laminar flow-based fuel cell working under critical conditions: The effect of parasitic current. Appl Energy 2012; 90: 87-93.

DOI: 10.1016/j.apenergy.2011.01.002

Google Scholar

[5] Kordesch K, Hacker V, Bachhiesl U. Direct methanol-air fuel cells with membranes plus circulating electrolyte. 22nd International Power Sources Symposium. Manchester, England: Elsevier Science Sa; 2001. pp.200-3.

DOI: 10.1016/s0378-7753(01)00491-8

Google Scholar