Selective Oxidation of Corn Starch in TEMPO-Mediated System

Yan Fang Hu; Xiao Dong Zhang; Zhao Guang Nie; Ya Cheng Xing; Bo Qun Lin; Li Li Song

doi:10.4028/www.scientific.net/AMR.1051.221

Paper Titles

Electrochemical Characteristics of TiAl Coating on Aluminum Alloy Surface by Supersonic Particles Deposition
p.199

Multiple Regression and Neural Network Based Characterization of Friction in Sheet Metal Forming
p.204

Investigation on the Discharge Behaviors of AZ31 and AZ61 Magnesium Alloys as Anode Material of Metal-Air Fuel Cells
p.211

Ultrasonic and Density Studies of D(+) Mannose with Aqueous Electrolytes at 303K
p.215

Selective Oxidation of Corn Starch in TEMPO-Mediated System
p.221

A Selective Plugging Agent for Horizontal Wells
p.225

Preparation of α High-Strength Gypsum from FGD Gypsum by Autoclaved Semi-Dry Process
p.230

Catalytic Activity of PILCS for Water Gas Shift Reaction of CO
p.237

Determination and Comparison of Material Properties of Commercial Wood-Plastic Composite Products
p.242

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1051Selective Oxidation of Corn Starch in...

Selective Oxidation of Corn Starch in TEMPO-Mediated System

Abstract:

With TEMPO-NaClO-NaBr as the selective oxidation system, the oxidized corn starch was prepared from the corn starch, substituting traditional pre-gelatinized corn starch. The relationship of the carboxyl mass fraction of the oxidized starch and the dosage of oxidant was studied under the conditions such as: the mass of the corn starch was 5.0g, the pH was 10.00, the reaction temperature was 20 °C. The structure of the oxidized corn starch was characterized by IR. The results showed that when the consumption of NaClO was 67.5 mL, the reaction time was 2.5 h, the carboxyl of oxidized starch can reach 10.60%.

You might also be interested in these eBooks

Applied Engineering Decisions in the Context of Sustainable Development

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 1051)

Pages:

221-224

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1051.221

Citation:

Cite this paper

Online since:

October 2014

Authors:

Yan Fang Hu*, Xiao Dong Zhang, Zhao Guang Nie, Ya Cheng Xing, Bo Qun Lin, Li Li Song

Keywords:

NaClO, Oxidized Starch, TEMPO

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] Z. Hu, Preparation of oxidized starch, Journal of Anhui Agricultural Sciences, 39(2011) 2339-2340.

Google Scholar

[2] Y.Q. Tan: Investigation of the starch oxidation mechanism, Farm Products Processing, 97 (2007) 47-51.

Google Scholar

[3] De Nooy A E J, Besemer A C. Highly selective tempo mediated oxidation of primary alcohol groups in polysaccharides, Recueil des Travaux Chimiques des Pays-Bas, 113(1994)165-166.

DOI: 10.1002/recl.19941130307

Google Scholar

[4] Chang P S, Robyt J F. Xidation of Primary Alcohol Groups of Naturally Occurring Polysaccharides with 2, 2, 6, 6-Tetramethyl-1-Piperidine Oxoammonium Ion, Journal of Carbohydrate Chemistry, 15 (1996) 819-830.

DOI: 10.1080/07328309608005694

Google Scholar

[5] Isogai A, Kato Y. Preparation of polyuronic acid from cellulose by TEMPO-mediated oxidation, Cellulose, 5 (1998) 153-164.

Google Scholar

[6] Tahir C, Vignon M R. TEMPO-oxidation of cellulose: synthesis and characterisation of polyglucuronans, Cellulose, 7 (2000), 177-188.

Google Scholar

[7] W.X. Han, W. Wang, W.J. Xu, Study on the selective oxidation of chitosan by TEMPO-NaOCl- NaBr and the structure of its productsSynthetic Technology and Application, 26. (2011), 8-10.

Google Scholar

[8] W.L. Qiu, Z.F. Wang, L.J. Huang, Progress on 2, 2, 6, 6-Tetramethylpiperineoxyl-mediated Oxidation of the Primary Alcohol of Carbohydrate Chemistry, 70(2007) 29-33.

Google Scholar