Development of Mica-Based Glass-Ceramic with 4 Mol% of Fluorapatite

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SiO2, Al2O3, MgO, MgF2, SrCO3, CaCO3, CaF2 and P2O5 were used to prepare machinable glass-ceramic with 4 mol% of fluorapatite for restorative dental applications. XRD showed that the glass heat treated at 792°C (the first crystallization temperature+20°C) for 6 hours consisted of calcium-mica, fluorapatite, strontium apatite, anorthite, forsterite, fluorite and stishovite crystalline phases. The microstructures of the resultant glass-ceramic, observed by SEM, were found to exhibit plate-like mica crystals and many tabular particles embedded in the mica phases. The particles, determined by EDS, were rich in calcium. The three-point bending strength (158 MPa) closely matched that of nature tooth. Average Vickers hardness of the received glass-ceramic (2.6 GPa) was lower than that of natural tooth.

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December 2014

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