Structural Change of Cathode with Pore Former Addition in SOFC

Article Preview

Abstract:

Solid oxide fuel cells (SOFCs) have been considered as a promising electricity-generation technology because of the relatively high efficiency in the conversion of chemical energy to electrical power. The cathode performance of solid oxide fuel cells (SOFC) depends substantially on its surface area, porosity and microstructure, and therefore the processing method used is very important in determining cathode performance. By optimizing the structural characteristic of the layer, the cathode performance during fuel cell performance can be fully maximized. Polyether ether ketone (PEEK) pore former was introduced in the processing method of cathode layer. The cathode layer was brush painted and sintered at 1200°C for 5 hours. TGA analysis is used to specify the sintering curve for the cathode layer. In addition, three point bending test is used to investigate the change in bending force with the addition of pore former. Characterization via FESEM allows inspection over the induced pore geometry and distribution along the layer. The study can produce a comprehensive structural analysis on the pore former addition in the precursor solution of the cathode layer for SOFC application.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

299-303

Citation:

Online since:

February 2015

Keywords:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S.C. Singhal, K. Kendall, High-temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications, Elsevier Advanced Technology, Oxford, 2003.

Google Scholar

[2] S. Jiang, S. Zhang, Y. Zhen., Deposition of Cr Species at  ( La , Sr )  ( Co , Fe ) O3 Cathodes of Solid Oxide Fuel Cells, J. Electrochem. Soc. 153 (2006) A127–A134.

DOI: 10.1149/1.2136077

Google Scholar

[3] H. Hamedani, K. Dahen, and D. Li., Fabrication of gradient porous LSM cathode by optimizing deposition parameters in ultrasonic spray pyrolysis, Mater. Sci. Eng. B153, (2008)

DOI: 10.1016/j.mseb.2008.07.006

Google Scholar

[4] M. Skovgaard, K.B. Andersen, K.K. Hansen., Pore former induced porosity in LSM/CGO cathodes for electrochemical cells for flue gas purification, Ceramics International 38 (2012) 1751-1754

DOI: 10.1016/j.ceramint.2011.09.052

Google Scholar

[5] M. Poon, O. Kesler., The influence of pore formers on the microstructure of plasma-sprayed NiO-YSZ anodes, Journal of Power Sources 210 (2012) 204-217

DOI: 10.1016/j.jpowsour.2012.02.046

Google Scholar

[6] L. Mingyi, Y. Bo, X. Jingming, C. Jing., Influence of pore formers on physical properties and microstructures of supporting cathodes of solid oxide electrolysis cells, International Journal of Hydrogen Energy 35 (2010) 2670-2674

DOI: 10.1016/j.ijhydene.2009.04.027

Google Scholar

[7] S.F. Corbin, P.S. Apte., Engineered Porosity via Tape Casting, Lamination and the Percolation of Pyrolyzable Particulates, Journal of American Ceramic Society 82 (7) (1999) 1693-1701

DOI: 10.1111/j.1151-2916.1999.tb01988.x

Google Scholar

[8] L. Nie, Z. Liu, M. Liu, L. Yang, Y. Zhang, M. Liu., Enhanced Performance of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-\delta (LSCF) Cathodes with Graded Microstructure Fabricated by Tape Casting, Journal of Electrochemical Science and Technology 1 (2010) 50-56

DOI: 10.5229/jecst.2010.1.1.050

Google Scholar

[9] A. Sanson, P. Pinasco, E. Roncari., Influence of pore formers on slurry composition and microstructure of tape cast supporting anodes for SOFCs, J. Eur. Ceram. Soc. 28 (2008) 1221–1226

DOI: 10.1016/j.jeurceramsoc.2007.10.001

Google Scholar

[10] J. Hu, Z. Lü, K. Chen, X. Huang, N. Ai, X. Du, C. Fu, J. Wang, W. Su., Effect of composite pore-former on the fabrication and performance of anode-supported membranes for SOFCs, J. Membr. Sci. 318 (2008) 445–451.

DOI: 10.1016/j.memsci.2008.03.008

Google Scholar

[11] J.J. Haslam, A.Q. Pham, B.W. Chung, J.F. Dicarlo, R.S. Glass., Effects of the Use of Pore Formers on Performance of an Anode Supported Solid Oxide Fuel Cell, J. Am. Ceram. Soc. 88 (2005) 513–518.

DOI: 10.1111/j.1551-2916.2005.00097.x

Google Scholar

[12] M.H.D Othman, N. Droushiotis, Z. Wu and G. Kelsall., Dual-layer hollow fibres with different anode structures for micro-tubular solid oxide fuel cells, Journal of Power Sources 205 (2012) 272-280

DOI: 10.1016/j.jpowsour.2012.01.002

Google Scholar

[13] N. Droushiotis, U. Doraswami, D. Ivey, M.H.D Othman, K. Li and G. Kelsall., Fabrication by Co-extrusion and electrochemical characterization of micro-tubular hollow fibre solid oxide fuel cells, Electrochemistry Communications 12 (6) (2010) 792-795

DOI: 10.1016/j.elecom.2010.03.035

Google Scholar

[14] M.H.D Othman, Z. Wu, N. Droushiotis, G. Kelsall and K. Li., Morphological studies of macrostructure of Ni–CGO anode hollow fibres for intermediate temperature solid oxide fuel cells, Journal of Membrane Science 360 (1-2) (2010) 410-417

DOI: 10.1016/j.memsci.2010.05.040

Google Scholar

[15] N. Droushiotis, A. Torabi, M. H. D Othman., Effects of lanthanum strontium cobalt ferrite (LSCF) cathode properties on hollow fibre micro-tubular SOFC performances, J Appl Electrochem 42 (2012) 517-526

DOI: 10.1007/s10800-012-0429-x

Google Scholar