Effects of Hydrothermal Duration on Synthesized Zeolite Rice Husk Particles

Abstract:

Zeolite particles were synthesized through in-situ extraction of silica from rice husk ash without seeding method in the absence of organic template by a static hydrothermal condition at various duration for 8, 12, and 24h. The effect amorphous silica content on hydrothermal duration of synthesis products was evaluated with X-ray diffraction (XRD), and field emission microscopy (FESEM). The present of zeolite Y without seeding method via XRD analysis show a mixture of zeolite A, Y and P. The transformation of amorphous rice husk particle was increased gradually with the increased of hydrothermal reaction. The FESEM images showed agglomerated cubic-shaped morphology of the powders with increase in crystallization reaction. .

• Periodical: Advanced Materials Research (Volume 1087)
• Pages: 447-451
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.1087.447
• Online since: February 2015
• Authors: Nurafiqah Rosman, Zawati Harun*
• Keywords: Hydrothermal, NaY Zeolite, Rice Husk Ash

References

[1] D. Prasetyoko, N. Ayunanda, H. Fansuri, D. Hartanto, Z. Ramli. Phase Transformation of Rice Husk Ash in the Synthesis of ZSM-5 without Organic Template, ITB J. Sci. 44 A (3) (2012) 250-262.

DOI: 10.5614/itbj.sci.2012.44.3.5

[2] A. Kumar, K. Mohanta, D. Kumar, O. Parkash. Properties and Industrial Applications of Rice husk: A review, International Journal of Emerging Technology and Advanced Engineering. 2 (10) (2012)

[3] X. Zhang, D. Tang, G. Jiang. Synthesis of zeolite NaA at room temperature: The effect of synthesis parameters on crystal size and its size distribution, Advanced Powder Technology. 24 (2013) 689–696.

DOI: 10.1016/j.apt.2012.12.010

[4] S. Bohra, D. Kundu, M.K. Naskarn. One-pot synthesis of NaA and NaP zeolite powders using agro-waste material and other low cost organic-free precursors, Ceramics International. 40 (2014) 1229–1234.

DOI: 10.1016/j.ceramint.2013.06.001

[5] W. Bo, M. Hongzhu. Factors affecting the synthesis of microsized NaY zeolite, Microporous and Mesoporous Materials. 25 (1998) 131–136.

DOI: 10.1016/s1387-1811(98)00195-4

[6] L.R.G. Araújoa, Jr.a C.L. Cavalcante, M., I. Fariasb Guedesb, J.M. Sasakib, P.T.C. Freireb, F.E.A. Melob, J. Mendes-Filhob Synthesis of Cubic Y Zeolite Using a Pulsed Microwave Heating System, Materials Research. 2(2) (1999) 105-109.

DOI: 10.1590/s1516-14391999000200011

[7] S. Sang, Z. Liu, P. Tian, Z. Liu, L. Qu , Y. Zhang. Synthesis of small crystals zeolite NaY, Materials Letters 60 (2006) 1131–1133.

DOI: 10.1016/j.matlet.2005.10.110

[8] J. Weitkamp and L. Puppe. Catalyst and zeolite: Fundamental and Application, Springer-Verlag Berlin Heidelberg New York, 1999.

[9] X. Liu, Z. Yan, H. Wang, Y. Luo. In-situ Synthesis of NaY Zeolite with Coal-Based Kaolin, Journal of Natural Gas Chemistry 12 (2003) 63-70.

[10] M.M. Rahman, N. Hasnida, W.B. Wan Nik. Preparation of Zeolite Y Using Local Raw Material Rice Husk as a Silica Source, J. Sci. Res. 1(2) (2009) 285-291.

DOI: 10.3329/jsr.v1i2.1777

[11] N. Taufiqurrahmi, A. R. Mohamed, S. Bhatia. Nanocrystalline Zeolite Y: Synthesis and Characterization, IOP Conf. Series: Materials Science and Engineering 17 (2011) 012030.

DOI: 10.1088/1757-899x/17/1/012030

[12] Y. Shen, M.P. Manning, J. Warzywoda, Jr. A. Sacco. Synthesis of Zeolite Y Nanocrystals from Clear Solutions, Mat. Res. Soc. Symp. Proc. 740 (2003) Materials Research Society 17.16

DOI: 10.1557/proc-740-i7.16