Hexacarboxylate-Bridged Dicopper (II) Paddle-Wheel-Based 3-D Metal-Organic Framework: Synthesis, Structure

Abstract:

Employed isophthalic acid and Quinoxaline as co-ligands, a new 3D metal-organic framework [{Cu₂(IPT)₂(QA)₂}₆]n ((H₂IPT= isophthalic acid, QA = Quinoxaline) had been prepared under hydrothermal condition. The compound crystallizes in the Rhombohedral space group R-3c, with cell parameters, a = 30.099(4) Å, b = 30.099(4) Å, c = 18.190(4) Å, a= β = γ = 90˚, V = 14271(4) nm³ and Z = 12. This 3D complex based on rhomboid-shaped structural unit [{Cu2(IPT)2(QA)2}6] shows unusual USF-1 topology. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to 300 °C.

• Periodical: Advanced Materials Research (Volume 1088)
• Pages: 314-317
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.1088.314
• Online since: February 2015
• Authors: Chang Feng Sun, Yan Yan Pang, Ying Zhao, Yu Yang*
• Keywords: Hydrothermal Synthesis, Metal Carboxylate, Metal-Organic Framework

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