Research on Thermodynamic Properties of Bioleaching Solution in Lean Nickel-Cobalt Ore by Pitzer - Meissner Model

Article Preview

Abstract:

In this paper, we jointly use the Pitzer model and the Meissner model to study thermodynamic laws of bioleaching solution in a lean nickel-cobalt ore in the Jilin Baishan, by using the Pitzer model to calculate activity coefficients of single electrolyte aqueous solutions and the Meissner model to calculate activity coefficients of components in the bioleaching solution. Also we studied the rules of activity coefficient of NiSO4 and CoSO4 in the solution. Results show that when separating and purifying foreign ions from bioleaching solution of the lean nickel-cobalt ore, the descending sequence of their ion concentration’s effect over the solution is Mg2+, Fe3+, Fe2+, Ni2+, Co2+ and Ca2+.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1092-1093)

Pages:

1455-1459

Citation:

Online since:

March 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Liu ML, Ruan R M, Wen J K, et al. 2007. Rare Metals. Sci. Vol. 26 (2007), pp.528-535.

Google Scholar

[2] Pitzer K S. J. Phys. Chem. Sci. Vol. 77(1973), pp.268-277.

Google Scholar

[3] Meissner H P. AIChE Journal. Sci. Vol. 18 (1972), pp.294-298.

Google Scholar

[4] Yao Y, Song P S, Zhang X. Oceanologia EtLimnologiaSinica. Cscd. Vol. 30(1999), pp.6-13.

Google Scholar

[5] Li D F. Yang X W. Xie B. Journal of Kunming Institute of Technology. Ei. Vol. 1 (1990), p.40 – 44.

Google Scholar

[6] Hee Talk Klm and William J. Frederick, Jr. J. Chem. Eng. Data. Sci. Vol. 33 (1988), pp.177-184.

Google Scholar

[7] Kobylin P, Kaskiala T, Salminen J. Eng. Chem. Res. Sci. Vol. 46 (2007), pp.2601-2608.

Google Scholar

[8] Li Z G : Basic research on hydrometallurgical of sulfide nickel ore (Northeastern University, China 2005).

Google Scholar