Synthesis, Crystal Structure and Optical Properties of Silver Complex with 2-Amino-4-Methylthiazole

Abstract:

The complex of 2-amino-4-methylthiazole with silver [Ag (C₄H₆N₂S)₂.(CH₃)₂CO] had been synthesized and characterized by elemental analysis, FT-IR and UV-vis spectra. Crystals of the complex were obtained through solvent diffusion method and the structure had been determined by single crystal X-ray diffraction. The nonlinear optical properties were investigated with the density functional theory method. The calculated results show that the complex has high hyperpolarizability of 316.8×10^-30 esu and the metal irons play an important role for the nonlinear optical properties.

• Periodical: Advanced Materials Research (Volume 1096)
• Pages: 143-146
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.1096.143
• Online since: April 2015
• Authors: Rui Ting Xue, Wei Song Sun, Si Rong Yu*
• Keywords: Crystal Structure, Nonlinear Optical Properties, Thiazoles

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