Preparation of Ni-P Alloy Composite Tube-Form Carbon Membrane for Gas Separation
A novel tube-form asymmetrical carbon membrane based on phenol-formaldehyde resin (PFR) is proposed in this paper. The membrane is composed of Ni-P alloy on exterior surface of carbon support membrane by electroless plating method after adding ferrous powders (<20&m) as active particles inside the membrane procurer. The results show that the H2, N2 and CO2 permeation rate through the composite Ni-P carbon membrane decrease and gas separation factors increase with increase of Fe content, and H2, N2 and CO2 permeation rates reach 0.44, 0.10 and 0.08 m3.m-2.s-1.MPa-1, respectively; H2/N2 and H2/CO2 separation factors are 4.2 and 5.5, respectively. The morphology of the membrane is measured by Scanning Electron Microscope (SEM).
Masayuki Nogami, Riguang Jin, Toshihiro Kasuga and Wantai Yang
J. F. Bai et al., "Preparation of Ni-P Alloy Composite Tube-Form Carbon Membrane for Gas Separation", Advanced Materials Research, Vols. 11-12, pp. 457-460, 2006