Impedance Behavior of Treated Methyl-Grafted Natural Rubber Polymer Electrolytes

Article Preview

Abstract:

Methyl-grafted natural rubber (MG30) was treated with N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) to enhance it anti-aging properties. The treated MG30 was used as polymer electrolyte by incorporating lithium trifluoromethane sulfonate (LiTF) through solution-cast technique. The impedance behavior of the sample has been carried out by analyzing the dielectric permittivity, dissipation factor, dielectric modulus and ionic conductivity as a function of temperature at different frequencies through impedance spectroscopy. Keywords: Methyl-grafted natural rubber, polymer electrolyte, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine, ionic conductivity, dielectric.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

217-222

Citation:

Online since:

June 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. M. M. Ali, R. H. Y. Subban, H. Bahron, M. Z. a. Yahya, and A. S. Kamisan, J. Power Sources, vol. 244, p.636–640, Dec. (2013).

DOI: 10.1016/j.jpowsour.2013.01.002

Google Scholar

[2] Z. Wen, Solid State Ionics, vol. 160, no. 1–2, p.141–148, May (2003).

Google Scholar

[3] D.E. Fenton, J.M. Parker, P.V. Wright, Polymer., vol. 14, p.589, (1973).

Google Scholar

[4] M. D. M.B. Armand, J.M. Chabagno, Second Int. Meet. Solid Electrolytes, no. extended abstract.

Google Scholar

[5] K. Kumutha, Y. Alias, and R. Said, Ionics., vol. 11, p.472–476, (2005).

Google Scholar

[6] K. Kumutha and Y. Alias, Spectrochim. Acta Part A Mol. Biomol. Spectrosc., vol. 64, no. 2, p.442–447, May (2006).

Google Scholar

[7] R. Idris, M. D. Glasse, R. J. Latham, R. G. Linford, and W. S. Schlindwein, vol. 94, p.206–211, (2001).

Google Scholar

[8] Y. Mizuno, M. Okubo, D. Asakura, T. Saito, E. Hosono, Y. Saito, K. Ohishi, T. Kudo, and H. Zhou, Electrochim. Acta, vol. 63, p.139–145, (2012).

DOI: 10.1016/j.electacta.2011.12.068

Google Scholar

[9] R. Baskaran, S. Selvasekarapandian, G. Hirankumar, and M. . Bhuvaneswari, J. Power Sources, vol. 134, no. 2, p.235–240, Aug. (2004).

DOI: 10.1016/j.jpowsour.2004.02.025

Google Scholar

[10] P. K. Varshney and S. Gupta, Ionics, vol. 17, no. 6, p.479–483, May (2011).

Google Scholar

[11] A. F. Bin Aziz and A. M. M. Ali, 2012 IEEE Colloq. Humanit. Sci. Eng., no. Chuser, p.719–723, Dec. (2012).

Google Scholar

[12] S. Ibrahim, S. M. M. Yasin, M. N. Ng, R. Ahmad, and M. R. Johan, Solid State Commun., vol. 151, no. 23, p.1828–1832, (2011).

DOI: 10.1016/j.ssc.2011.08.015

Google Scholar

[13] A. M. M. Ali, R. H. Y. Subban, H. Bahron, T. Winie, F. Latif, and M. Z. A. Yahya, Ionics., vol. 14, no. 6, p.491–500, Jan. (2008).

DOI: 10.1007/s11581-007-0199-3

Google Scholar

[14] A. M. M. Ali, M. Z. A. Yahya, H. Bahron, and R. H. Y. Subban, Ionics (Kiel)., vol. 12, no. 4–5, p.303–307, (2006).

Google Scholar

[15] C. Kuo, C. Huang, B. Chen, W. Li, and P. Chen, vol. 8, p.3834–3850, (2013).

Google Scholar

[16] Shahzada Ahmad, S. A. Agnihotry, and S. Ahmad, J. Appl. Polym. …, p.3042–3048, (2008).

Google Scholar

[17] X. -L. Wu, S. Xin, H. -H. Seo, J. Kim, Y. -G. Guo, and J. -S. Lee, Solid State Ionics, vol. 186, no. 1, p.1–6, Mar. (2011).

Google Scholar

[18] A. M. M. Ali, M. Z. A. Yahya, H. Bahron, R. H. Y. Subban, M. K. Harun, and I. Atan, Mater. Lett., vol. 61, no. 10, p.2026–2029, Apr. (2007).

DOI: 10.1016/j.matlet.2006.08.008

Google Scholar

[19] S. Jung, D. W. Kim, S. D. Lee, M. Cheong, and D. Q. Nguyen, Fillers for Solid-State Polymer Electrolytes : Highlight, vol. 30, no. 10, (2009).

Google Scholar

[20] H. Nithya, S. Selvasekarapandian, D. Arun Kumar, a. Sakunthala, M. Hema, P. Christopherselvin, J. Kawamura, R. Baskaran, and C. Sanjeeviraja, Mater. Chem. Phys., vol. 126, no. 1–2, p.404–408, Mar. (2011).

DOI: 10.1016/j.matchemphys.2010.10.047

Google Scholar

[21] M. Hema, S. Selvasekarapandian, D. Arunkumar, a. Sakunthala, and H. Nithya, J. Non. Cryst. Solids, vol. 355, no. 2, p.84–90, Jan. (2009).

DOI: 10.1016/j.jnoncrysol.2008.10.009

Google Scholar

[22] N. I. Harun, R. M. Ali, A. M. M. Ali, and M. Z. A. Yahya, Ionics., vol. 18, no. 6, p.599–606, Dec. (2011).

Google Scholar

[23] J. Ji, B. Li, and W. -H. Zhong, Electrochim. Acta, vol. 55, no. 28, p.9075–9082, Dec. (2010).

Google Scholar

[24] S. Ibrahim, S. M. Mohd Yasin, N. M. Nee, R. Ahmad, and M. R. Johan, Solid State Commun., vol. 152, no. 5, p.426–434, Mar. (2012).

DOI: 10.1016/j.ssc.2011.11.037

Google Scholar