Effect of Al2O3  on the Electrical Conductivity of MgI2-Mg3(PO4)2 Solid Electrolyte

Azizah Hanom Ahmad; A. Aziz

doi:10.4028/www.scientific.net/AMR.1112.279

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1112Effect of Al2O3 on the Electrical Conductivity of...

Effect of Al₂O₃ on the Electrical Conductivity of MgI₂-Mg₃(PO₄)₂ Solid Electrolyte

Abstract:

MgI₂ and Mg₃(PO₄)₂were mixed in varied compositions and the mixture was subjected to ball milling and sintering process. The optimum composition of the binary system with the maximum conductivity of 5.72 x10^-4 Scm^-1 at room temperature was obtained and used to study the effect of ceramic filler. A small amount of Al₂O₃ was added to the 0.7 Mg₃(PO₄)₂ 0.3 MgI_2.The effect of ceramic filler on the electrical conductivity of the binary compound is investigated by Electrical Impedance Spectroscopy (EIS) technique in the frequency range from 50 Hz to 1 MHz. The conductivity was enhanced to 1.08 x 10^-3 Scm^-1 when 4 wt. % of Al₂O₃was added. Further characterization was performed by using Infrared (FTIR) technique. From FTIR spectra, the variation in the peak intensity and shifting were observed which is due to the interaction between O-OH on the filler grain surface.

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Periodical:

Advanced Materials Research (Volume 1112)

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279-281

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1112.279

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Online since:

July 2015

Authors:

Azizah Hanom Ahmad*, A. Aziz

Keywords:

Alumina, Ceramic Filler, Ionic Conductivity, Magnesium Solid Electrolyte

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References

[1] G. G. Kumar and N. Munichandraiah, J. Power Sources. 102 (2001) 46-54.

Google Scholar

[2] T. Inada, T. Kobayashi, N. Sonoyama, A. Yamada, S. Kondo, M. Naga, and R. Kanno, J Power Sources. 194 (2009) 1085–1088.

DOI: 10.1016/j.jpowsour.2009.06.100

Google Scholar

[3] N.H. Kaus and A.H. Ahmad, J Ionics. 15( 2009) 197-201.

Google Scholar

[4] A.H. Ahmad and A.K. Arof, J Ionics. 8 ( 2002) 433-438.

Google Scholar

[5] A.H. Ahmad and A.K. Arof, J Ionics. 10 (2004) 200-205.

Google Scholar

[6] A.H. Ahmad, N. Hassan, and M.A. Abrani, J Ionics. 20 (2014) 389-397.

Google Scholar

[7] R. Chandrasekaran, M. Koh, A. Yamauchi, and M. Ishikawa, J Power Sources. 195 (2010) 662.

Google Scholar

[8] O. Chusid, Y. Gofer, H. Gizbar, Y. Vestfrid, E. Levi, and D. Aurbach, Riech, Adv. Mater. 15 (2003) 627.

DOI: 10.1002/adma.200304415

Google Scholar

[9] N. Yoshimoto, S. Yakushiji, M. Ishikawa, and M. Morita, Solid State Ionics. 152-153 (2002) 259.

DOI: 10.1016/s0167-2738(02)00308-9

Google Scholar

[10] D. K Rai, S.A. Hashmi, Y. Kumar, and G. P Pandey, Electro active polymers, materials and Devices. 2 (2009) 407.

Google Scholar

[11] Ramesh, S. C. Lu , E. Morris, J. of the Taiwan Institute of Chemical Engineers 43 (2012) 806.

Google Scholar

[12] S. Jung, D. Won Kim, S. D. Lee, M. Cheong, D.Q. Nguen, B.W. Cho and H.S. Kim, Bull. Korean Chem. Soc. 30 (10) (2009) 30.

Google Scholar

[13] M.R. Johan, O.H. Shy, S. Ibrahim , S. M M. Yassin, T.Y. Hui, Solid State Ionics 196 (2011) 41.

Google Scholar

[14] S. Ramesh and M.F. Chai, Materials Science and Engineering: B, 139(2-3), (2007) 240–245.

Google Scholar

[15] Ramesh, S.C. Lu , E. Morris, J. of the Taiwan Inst. of Chemical Engineers 43 (2012) 806–812.

Google Scholar